1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds

Ji Hee Kim, Devalina Ray, Chang Seop Hong, Jin Wook Han, Chang Ho Oh

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Isochromenylium-4-ylplatinum(ii) species, generated from 1-(2-alkynylphenyl)hex-5-en-1-ones and Pt(ii), reacted with a pendant olefin via [3+2] cycloaddition to form tetracyclic Pt-carbene complexes, which underwent C-H insertion with a benzyloxy group at δ or ε positions to give highly complex polycycles, which are otherwise hard to access.

Original languageEnglish
Pages (from-to)5690-5692
Number of pages3
JournalChemical Communications
Volume49
Issue number50
DOIs
Publication statusPublished - 2013 Jun 25

Fingerprint

Cycloaddition
Cycloaddition Reaction
Alkenes
Olefins
carbene

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds. / Kim, Ji Hee; Ray, Devalina; Hong, Chang Seop; Han, Jin Wook; Oh, Chang Ho.

In: Chemical Communications, Vol. 49, No. 50, 25.06.2013, p. 5690-5692.

Research output: Contribution to journalArticle

Kim, Ji Hee ; Ray, Devalina ; Hong, Chang Seop ; Han, Jin Wook ; Oh, Chang Ho. / 1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds. In: Chemical Communications. 2013 ; Vol. 49, No. 50. pp. 5690-5692.
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