25,27-(6-Tosyl-3,9-dioxa-6-azaundecane-1,11 -diyldioxy)-26,28-(3,6,9 trioxaundecane-1,11 -diyldioxy)calix[4]arene

Jong Seung Kim, Won Lee Ku, Jeong Ah Rim, William P. Jensen, Lee, Moon Jib Kim, Jin Gyu Kim, Il Hwan Suh

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A new calix[4]-crowned azacrown ether, C51H59NO11S, consisting of four phenyl rings in a 1,3-aIternate conformation was synthesized from the reaction of 25,27-bis(5-chloro-3oxapenty!oxy)calix[4]crown-5 and p-toluenesulfonamide in the presence of Cs2CO3. A crown-5 loop was attached on the two facing lower rims of the calix[4]arene and the N-tosyl azacrown group was attached on the other set of lower rims of the calix[4]arene backbone. This molecule seems to offer an inside cavity for the formation of a host-guest complex.

Original languageEnglish
Pages (from-to)1369-1371
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number11
DOIs
Publication statusPublished - 2000

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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