2D reentrant auxetic structures of graphene/CNT networks for omnidirectionally stretchable supercapacitors

Byoung Soo Kim, Kangsuk Lee, Seulki Kang, Soyeon Lee, Jun Beom Pyo, In Suk Choi, Kookheon Char, Jong Hyuk Park, Sang-Soo Lee, Jonghwi Lee, Jeong Gon Son

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Stretchable energy storage systems are essential for the realization of implantable and epidermal electronics. However, high-performance stretchable supercapacitors have received less attention because currently available processing techniques and material structures are too limited to overcome the trade-off relationship among electrical conductivity, ion-accessible surface area, and stretchability of electrodes. Herein, we introduce novel 2D reentrant cellular structures of porous graphene/CNT networks for omnidirectionally stretchable supercapacitor electrodes. Reentrant structures, with inwardly protruded frameworks in porous networks, were fabricated by the radial compression of vertically aligned honeycomb-like rGO/CNT networks, which were prepared by a directional crystallization method. Unlike typical porous graphene structures, the reentrant structure provided structure-assisted stretchability, such as accordion and origami structures, to otherwise unstretchable materials. The 2D reentrant structures of graphene/CNT networks maintained excellent electrical conductivities under biaxial stretching conditions and showed a slightly negative or near-zero Poisson's ratio over a wide strain range because of their structural uniqueness. For practical applications, we fabricated all-solid-state supercapacitors based on 2D auxetic structures. A radial compression process up to 1/10th densified the electrode, significantly increasing the areal and volumetric capacitances of the electrodes. Additionally, vertically aligned graphene/CNT networks provided a plentiful surface area and induced sufficient ion transport pathways for the electrodes. Therefore, they exhibited high gravimetric and areal capacitance values of 152.4 F g-1 and 2.9 F cm-2, respectively, and had an excellent retention ratio of 88% under a biaxial strain of 100%. Auxetic cellular and vertically aligned structures provide a new strategy for the preparation of robust platforms for stretchable energy storage electrodes.

Original languageEnglish
Pages (from-to)13272-13280
Number of pages9
JournalNanoscale
Volume9
Issue number35
DOIs
Publication statusPublished - 2017 Sep 21
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science(all)

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    Kim, B. S., Lee, K., Kang, S., Lee, S., Pyo, J. B., Choi, I. S., Char, K., Park, J. H., Lee, S-S., Lee, J., & Son, J. G. (2017). 2D reentrant auxetic structures of graphene/CNT networks for omnidirectionally stretchable supercapacitors. Nanoscale, 9(35), 13272-13280. https://doi.org/10.1039/c7nr02869e