[60]Fullerene as a versatile four-electron donor ligand

Hyunjoon Song, Kwangyeol Lee, Moon Gun Choi, Joon T. Park

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ 3112-C60 ) (2; R = CH2Ph), is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3121-C60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6 H4)(PPh3)(μ-PPh2)(μ-η2 2-C60) (3), with an Os-Os bond cleavage.

Original languageEnglish
Pages (from-to)1756-1758
Number of pages3
JournalOrganometallics
Volume21
Issue number9
DOIs
Publication statusPublished - 2002 Apr 29
Externally publishedYes

Fingerprint

fullerenes
cleavage
Substitution reactions
substitutes
Ligands
ligands
Electrons
electrons
fullerene C60

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

[60]Fullerene as a versatile four-electron donor ligand. / Song, Hyunjoon; Lee, Kwangyeol; Choi, Moon Gun; Park, Joon T.

In: Organometallics, Vol. 21, No. 9, 29.04.2002, p. 1756-1758.

Research output: Contribution to journalArticle

Song, Hyunjoon ; Lee, Kwangyeol ; Choi, Moon Gun ; Park, Joon T. / [60]Fullerene as a versatile four-electron donor ligand. In: Organometallics. 2002 ; Vol. 21, No. 9. pp. 1756-1758.
@article{e49cd000c05945978f4e436d4450f92b,
title = "[60]Fullerene as a versatile four-electron donor ligand",
abstract = "A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ 3-η1:η1:η2-C60 ) (2; R = CH2Ph), is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3-η 1:η2:η1-C60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6 H4)(PPh3)(μ-PPh2)(μ-η2 :η2-C60) (3), with an Os-Os bond cleavage.",
author = "Hyunjoon Song and Kwangyeol Lee and Choi, {Moon Gun} and Park, {Joon T.}",
year = "2002",
month = "4",
day = "29",
doi = "10.1021/om020038f",
language = "English",
volume = "21",
pages = "1756--1758",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "9",

}

TY - JOUR

T1 - [60]Fullerene as a versatile four-electron donor ligand

AU - Song, Hyunjoon

AU - Lee, Kwangyeol

AU - Choi, Moon Gun

AU - Park, Joon T.

PY - 2002/4/29

Y1 - 2002/4/29

N2 - A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ 3-η1:η1:η2-C60 ) (2; R = CH2Ph), is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3-η 1:η2:η1-C60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6 H4)(PPh3)(μ-PPh2)(μ-η2 :η2-C60) (3), with an Os-Os bond cleavage.

AB - A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ 3-η1:η1:η2-C60 ) (2; R = CH2Ph), is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3-η 1:η2:η1-C60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6 H4)(PPh3)(μ-PPh2)(μ-η2 :η2-C60) (3), with an Os-Os bond cleavage.

UR - http://www.scopus.com/inward/record.url?scp=0000628319&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000628319&partnerID=8YFLogxK

U2 - 10.1021/om020038f

DO - 10.1021/om020038f

M3 - Article

AN - SCOPUS:0000628319

VL - 21

SP - 1756

EP - 1758

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 9

ER -