[60]Fullerene-metal cluster complexes: Novel bonding modes and electronic communication

Kwangyeol Lee; Hyunjoon Song; Joon T. Park

doi:10.1021/ar020149a

[60]Fullerene-metal cluster complexes: Novel bonding modes and electronic communication

Kwangyeol Lee, Hyunjoon Song, Joon T. Park

Research output: Contribution to journal › Article › peer-review

138 Citations (Scopus)

Abstract

[60]Fullerene can bind a variety of metal clusters via η²-C₆₀, μ-η²: η²-C₆₀, and μ₃-η²:η²: η²-C₆₀ π-type bonding modes. Multiple C₆₀ additions to a single cluster core have also been demonstrated. Modification of the coordination sphere of cluster moieties has resulted in novel transformation of the coordination mode of the C₆₀ ligand between π and σ (μ₃-η¹:η¹: η²-C₆₀ and μ₃-η¹:η²: η¹-C₆₀) types as well as reversible interconversion between μ₃-η²:η²: η²-C₆₀ and μ-η²:η²-C₆₀. The μ₃-η²:η²:η² metal cluster complexes show remarkable electrochemical stability and an unusually strong electronic communication between C₆₀ and metal cluster centers.

Original language	English
Pages (from-to)	78-86
Number of pages	9
Journal	Accounts of Chemical Research
Volume	36
Issue number	1
DOIs	https://doi.org/10.1021/ar020149a
Publication status	Published - 2003 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "[60]Fullerene-metal cluster complexes: Novel bonding modes and electronic communication",

abstract = "[60]Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2:η2: η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also been demonstrated. Modification of the coordination sphere of cluster moieties has resulted in novel transformation of the coordination mode of the C60 ligand between π and σ (μ3-η1:η1: η2-C60 and μ3-η1:η2: η1-C60) types as well as reversible interconversion between μ3-η2:η2: η2-C60 and μ-η2:η2-C60. The μ3-η2:η2:η2 metal cluster complexes show remarkable electrochemical stability and an unusually strong electronic communication between C60 and metal cluster centers.",

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T1 - [60]Fullerene-metal cluster complexes

T2 - Novel bonding modes and electronic communication

AU - Lee, Kwangyeol

AU - Song, Hyunjoon

AU - Park, Joon T.

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Y1 - 2003/1/1

N2 - [60]Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2:η2: η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also been demonstrated. Modification of the coordination sphere of cluster moieties has resulted in novel transformation of the coordination mode of the C60 ligand between π and σ (μ3-η1:η1: η2-C60 and μ3-η1:η2: η1-C60) types as well as reversible interconversion between μ3-η2:η2: η2-C60 and μ-η2:η2-C60. The μ3-η2:η2:η2 metal cluster complexes show remarkable electrochemical stability and an unusually strong electronic communication between C60 and metal cluster centers.

AB - [60]Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2:η2: η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also been demonstrated. Modification of the coordination sphere of cluster moieties has resulted in novel transformation of the coordination mode of the C60 ligand between π and σ (μ3-η1:η1: η2-C60 and μ3-η1:η2: η1-C60) types as well as reversible interconversion between μ3-η2:η2: η2-C60 and μ-η2:η2-C60. The μ3-η2:η2:η2 metal cluster complexes show remarkable electrochemical stability and an unusually strong electronic communication between C60 and metal cluster centers.

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[60]Fullerene-metal cluster complexes: Novel bonding modes and electronic communication

Abstract

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