Abstract
[60]Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2:η2: η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also been demonstrated. Modification of the coordination sphere of cluster moieties has resulted in novel transformation of the coordination mode of the C60 ligand between π and σ (μ3-η1:η1: η2-C60 and μ3-η1:η2: η1-C60) types as well as reversible interconversion between μ3-η2:η2: η2-C60 and μ-η2:η2-C60. The μ3-η2:η2:η2 metal cluster complexes show remarkable electrochemical stability and an unusually strong electronic communication between C60 and metal cluster centers.
| Original language | English |
|---|---|
| Pages (from-to) | 78-86 |
| Number of pages | 9 |
| Journal | Accounts of Chemical Research |
| Volume | 36 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2003 Jan 1 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
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[60]Fullerene-metal cluster complexes : Novel bonding modes and electronic communication. / Lee, Kwangyeol; Song, Hyunjoon; Park, Joon T.
In: Accounts of Chemical Research, Vol. 36, No. 1, 01.01.2003, p. 78-86.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - [60]Fullerene-metal cluster complexes
T2 - Novel bonding modes and electronic communication
AU - Lee, Kwangyeol
AU - Song, Hyunjoon
AU - Park, Joon T.
PY - 2003/1/1
Y1 - 2003/1/1
N2 - [60]Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2:η2: η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also been demonstrated. Modification of the coordination sphere of cluster moieties has resulted in novel transformation of the coordination mode of the C60 ligand between π and σ (μ3-η1:η1: η2-C60 and μ3-η1:η2: η1-C60) types as well as reversible interconversion between μ3-η2:η2: η2-C60 and μ-η2:η2-C60. The μ3-η2:η2:η2 metal cluster complexes show remarkable electrochemical stability and an unusually strong electronic communication between C60 and metal cluster centers.
AB - [60]Fullerene can bind a variety of metal clusters via η2-C60, μ-η2: η2-C60, and μ3-η2:η2: η2-C60 π-type bonding modes. Multiple C60 additions to a single cluster core have also been demonstrated. Modification of the coordination sphere of cluster moieties has resulted in novel transformation of the coordination mode of the C60 ligand between π and σ (μ3-η1:η1: η2-C60 and μ3-η1:η2: η1-C60) types as well as reversible interconversion between μ3-η2:η2: η2-C60 and μ-η2:η2-C60. The μ3-η2:η2:η2 metal cluster complexes show remarkable electrochemical stability and an unusually strong electronic communication between C60 and metal cluster centers.
UR - http://www.scopus.com/inward/record.url?scp=0037244788&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037244788&partnerID=8YFLogxK
U2 - 10.1021/ar020149a
DO - 10.1021/ar020149a
M3 - Article
C2 - 12534307
AN - SCOPUS:0037244788
VL - 36
SP - 78
EP - 86
JO - The BMJ
JF - The BMJ
SN - 0730-6512
IS - 1
ER -