A chiral pentadecanuclear metallamacrocycle with a sextuple twisted möbius topology

Rohith P. John, Mira Park, Dohyun Moon, Kyungjin Lee, Seunghee Hong, Yang Zou, Seop Hong Chang, Soo Lah Myoung

Research output: Contribution to journalArticlepeer-review

63 Citations (Scopus)

Abstract

A C3 symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N-phenylpropiolyl salicylhydrazide (H3L), and a manganese ion. The combination of a narrow Cα-Cβ region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Möbius topology was stabilized by extensive weak intramolecular interactions.

Original languageEnglish
Pages (from-to)14142-14143
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number46
DOIs
Publication statusPublished - 2007 Nov 21

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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