A dipyrenyl calixazacrown as a selective sensor for Pb2+

Sang Hoon Kim; Abdelwaheb Hamdi; Young Hoon Lee; Joung Hae Lee; Jong Seung Kim; Jacques Vicens

doi:10.1007/s10847-009-9667-x

A dipyrenyl calixazacrown as a selective sensor for Pb²⁺

Sang Hoon Kim, Abdelwaheb Hamdi, Young Hoon Lee, Joung Hae Lee, Jong Seung Kim, Jacques Vicens

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

New fluorogenic calixazacrown (5) bearing two pyrene amide pendent groups has been synthesized. Based on ratiometric changes of monomer and excimer emissions, 5 has been found to act as a selective sensor for Pb²⁺ ion due to conformational change upon chelation of Pb²⁺ within 1:1 complex.

Original language	English
Pages (from-to)	133-137
Number of pages	5
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	66
Issue number	1
DOIs	https://doi.org/10.1007/s10847-009-9667-x
Publication status	Published - 2010 Jan

Keywords

Calixarenes
Complexation
Detection
Excimer
Fluorescence
Lead

ASJC Scopus subject areas

Food Science
Chemistry(all)
Condensed Matter Physics

Access to Document

10.1007/s10847-009-9667-x

Cite this

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title = "A dipyrenyl calixazacrown as a selective sensor for Pb2+",

abstract = "New fluorogenic calixazacrown (5) bearing two pyrene amide pendent groups has been synthesized. Based on ratiometric changes of monomer and excimer emissions, 5 has been found to act as a selective sensor for Pb2+ ion due to conformational change upon chelation of Pb2+ within 1:1 complex.",

keywords = "Calixarenes, Complexation, Detection, Excimer, Fluorescence, Lead",

author = "Kim, {Sang Hoon} and Abdelwaheb Hamdi and Lee, {Young Hoon} and Lee, {Joung Hae} and Kim, {Jong Seung} and Jacques Vicens",

note = "Funding Information: Acknowledgments This work was supported by the SRC (KOSEF) grant (No. R11-2005-008-00000-0) and KRF (KRF-2008-313-C00501) and the Creative Research Initiative Program of the Ministry of Education, Science and Technology of the Korean Government and by l{\textquoteright}Agence Universitaire de la Francophonie (A.H.).",

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AU - Kim, Sang Hoon

AU - Hamdi, Abdelwaheb

AU - Lee, Young Hoon

AU - Lee, Joung Hae

AU - Kim, Jong Seung

AU - Vicens, Jacques

N1 - Funding Information: Acknowledgments This work was supported by the SRC (KOSEF) grant (No. R11-2005-008-00000-0) and KRF (KRF-2008-313-C00501) and the Creative Research Initiative Program of the Ministry of Education, Science and Technology of the Korean Government and by l’Agence Universitaire de la Francophonie (A.H.).

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N2 - New fluorogenic calixazacrown (5) bearing two pyrene amide pendent groups has been synthesized. Based on ratiometric changes of monomer and excimer emissions, 5 has been found to act as a selective sensor for Pb2+ ion due to conformational change upon chelation of Pb2+ within 1:1 complex.

AB - New fluorogenic calixazacrown (5) bearing two pyrene amide pendent groups has been synthesized. Based on ratiometric changes of monomer and excimer emissions, 5 has been found to act as a selective sensor for Pb2+ ion due to conformational change upon chelation of Pb2+ within 1:1 complex.

KW - Calixarenes

KW - Complexation

KW - Detection

KW - Excimer

KW - Fluorescence

KW - Lead

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