A facile and scalable fabrication method for thin film composite reverse osmosis membranes: dual-layer slot coating

Sung Joon Park, Won Gi Ahn, Wansuk Choi, Sang Hee Park, Jong Suk Lee, Hyun Wook Jung, Jung-hyun Lee

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

We report on a unique, facile and scalable fabrication technique, dual-layer slot coating (DSC) for high performance polyamide (PA) thin film composite (TFC) reverse osmosis (RO) membranes. DSC allows the simultaneous and continuous spreading of two reactive monomer solutions to create an unsupported PA layer via in situ polymerization, which is then adhered onto a porous support to form a membrane. DSC facilitates the characterization of the PA layer structure by easily isolating it. The DSC-assembled PA layer exhibits a thinner and smoother structure with a more wettable and less negatively charged surface than the one prepared via conventional interfacial polymerization (IP), which was attributed to the uniformly expedited amine (MPD) diffusion at the bulk liquid interface during film formation. As a result, DSC enables the formation of an extremely thin (∼9 nm) and dense PA layer using a very low MPD concentration, which is not feasible by conventional IP. Importantly, the DSC-assembled membrane shows an excellent water flux and NaCl rejection, exceeding both IP control and commercial RO membranes. The DSC technique will open a new paradigm for the fabrication of TFC membranes with strong commercial potential due to its simplicity, scalability and high performance.

Original languageEnglish
Pages (from-to)6648-6655
Number of pages8
JournalJournal of Materials Chemistry A
Volume5
Issue number14
DOIs
Publication statusPublished - 2017

Fingerprint

Osmosis membranes
Reverse osmosis
Nylons
Polyamides
Fabrication
Thin films
Coatings
Composite materials
Polymerization
Membranes
Coating techniques
Composite membranes
Amines
Scalability
Monomers
Fluxes
Water
Liquids

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

A facile and scalable fabrication method for thin film composite reverse osmosis membranes : dual-layer slot coating. / Park, Sung Joon; Ahn, Won Gi; Choi, Wansuk; Park, Sang Hee; Lee, Jong Suk; Jung, Hyun Wook; Lee, Jung-hyun.

In: Journal of Materials Chemistry A, Vol. 5, No. 14, 2017, p. 6648-6655.

Research output: Contribution to journalArticle

Park, Sung Joon ; Ahn, Won Gi ; Choi, Wansuk ; Park, Sang Hee ; Lee, Jong Suk ; Jung, Hyun Wook ; Lee, Jung-hyun. / A facile and scalable fabrication method for thin film composite reverse osmosis membranes : dual-layer slot coating. In: Journal of Materials Chemistry A. 2017 ; Vol. 5, No. 14. pp. 6648-6655.
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