A facile one-pot hydrothermal synthesis of hydroxyapatite/biochar nanocomposites

Adsorption behavior and mechanisms for the removal of copper(II) from aqueous media

Kyung Won Jung, Seon Yong Lee, Jae Woo Choi, Young Jae Lee

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In this study, hydroxyapatite/biochar nanocomposites (HAP/BC-NCs) were synthesized through a simple one-pot hydrothermal process and utilized as an adsorbent for the removal of copper(II) from aqueous media. Characterization results revealed that rod-shaped HAP nanoparticles were successfully incorporated on the surfaces of synthesized HAP/BC-NCs. A set of systematically designed batch experiments were carried out to determine the influences of adsorbent dosage, solution pH, ionic strength, and temperature on the adsorption behavior of the HAP/BC-NCs. Overall findings from batch experiments and extended X-ray absorption fine structure analysis demonstrated that the potential mechanisms responsible for the removal of Cu(II) from aqueous media are cation exchange between Cu 2+ in solution and Ca 2+ in the HAP on the surfaces of the as-synthesized nanocomposites and the formation of inner-sphere surface complexes on the surfaces of the HAP/BC-NCs. Kinetic studies revealed that the adsorption process follows the pseudo-second-order model and that the overall adsorption rate is controlled by film diffusion as the dominant mechanism and intraparticle diffusion as a secondary mechanism. Adsorption isotherms were accurately represented by a Langmuir isotherm model and the maximum adsorption capacity was determined to be 99.01 mg/g at 298 K, which represents a higher efficiency for Cu(II) adsorption compared to previously reported composite materials. Thermodynamic analysis indicated that the process is thermodynamically spontaneous and endothermic process. Overall, the findings presented in this paper suggest that HAP/BC-NCs have promising applicability for the removal of heavy metals from aqueous media as an alternative, low-cost, and eco-friendly adsorbent for environmental remediation.

Original languageEnglish
Pages (from-to)529-541
Number of pages13
JournalChemical Engineering Journal
Volume369
DOIs
Publication statusPublished - 2019 Aug 1

Fingerprint

Hydrothermal synthesis
Durapatite
Hydroxyapatite
Copper
Nanocomposites
copper
adsorption
Adsorption
Adsorbents
isotherm
X ray absorption
Heavy Metals
Ionic strength
Adsorption isotherms
Heavy metals
Isotherms
Cations
Ion exchange
Positive ions
Experiments

Keywords

  • Biochar
  • Cation exchange
  • Copper
  • Hydroxyapatite
  • Inner-sphere surface complexation
  • One-pot hydrothermal synthesis

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

A facile one-pot hydrothermal synthesis of hydroxyapatite/biochar nanocomposites : Adsorption behavior and mechanisms for the removal of copper(II) from aqueous media. / Jung, Kyung Won; Lee, Seon Yong; Choi, Jae Woo; Lee, Young Jae.

In: Chemical Engineering Journal, Vol. 369, 01.08.2019, p. 529-541.

Research output: Contribution to journalArticle

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abstract = "In this study, hydroxyapatite/biochar nanocomposites (HAP/BC-NCs) were synthesized through a simple one-pot hydrothermal process and utilized as an adsorbent for the removal of copper(II) from aqueous media. Characterization results revealed that rod-shaped HAP nanoparticles were successfully incorporated on the surfaces of synthesized HAP/BC-NCs. A set of systematically designed batch experiments were carried out to determine the influences of adsorbent dosage, solution pH, ionic strength, and temperature on the adsorption behavior of the HAP/BC-NCs. Overall findings from batch experiments and extended X-ray absorption fine structure analysis demonstrated that the potential mechanisms responsible for the removal of Cu(II) from aqueous media are cation exchange between Cu 2+ in solution and Ca 2+ in the HAP on the surfaces of the as-synthesized nanocomposites and the formation of inner-sphere surface complexes on the surfaces of the HAP/BC-NCs. Kinetic studies revealed that the adsorption process follows the pseudo-second-order model and that the overall adsorption rate is controlled by film diffusion as the dominant mechanism and intraparticle diffusion as a secondary mechanism. Adsorption isotherms were accurately represented by a Langmuir isotherm model and the maximum adsorption capacity was determined to be 99.01 mg/g at 298 K, which represents a higher efficiency for Cu(II) adsorption compared to previously reported composite materials. Thermodynamic analysis indicated that the process is thermodynamically spontaneous and endothermic process. Overall, the findings presented in this paper suggest that HAP/BC-NCs have promising applicability for the removal of heavy metals from aqueous media as an alternative, low-cost, and eco-friendly adsorbent for environmental remediation.",
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