A highly selective colorimetric and ratiometric two-photon fluorescent probe for fluoride ion detection

Jun Feng Zhang; Chang Su Lim; Sankarprasad Bhuniya; Bong-Rae Cho; Jong Seung Kim

doi:10.1021/ol200072e

A highly selective colorimetric and ratiometric two-photon fluorescent probe for fluoride ion detection

Jun Feng Zhang, Chang Su Lim, Sankarprasad Bhuniya, Bong-Rae Cho, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

277 Citations (Scopus)

Abstract

A naphthalimide-based highly selective colorimetric and ratiometric fluorescent probe for the fluoride ion displayed both one-and two-photon ratiometric changes. Upon reaction with the F^- (TBA⁺ and Na⁺ salts) anion in CH₃CN as well as in aqueous buffer solution, probe 1 shows dramatic color changes from colorless to jade-green and remarkable ratiometric fluorescence enhancements signals. These properties are mechanistically ascribed to a fluoride-triggered Si-O bond cleavage that resulted in a green fluorescent 4-amino-1,8-naphthalimide.(Figure Presented)

Original language	English
Pages (from-to)	1190-1193
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	5
DOIs	https://doi.org/10.1021/ol200072e
Publication status	Published - 2011 Mar 4

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "A highly selective colorimetric and ratiometric two-photon fluorescent probe for fluoride ion detection",

abstract = "A naphthalimide-based highly selective colorimetric and ratiometric fluorescent probe for the fluoride ion displayed both one-and two-photon ratiometric changes. Upon reaction with the F- (TBA+ and Na+ salts) anion in CH3CN as well as in aqueous buffer solution, probe 1 shows dramatic color changes from colorless to jade-green and remarkable ratiometric fluorescence enhancements signals. These properties are mechanistically ascribed to a fluoride-triggered Si-O bond cleavage that resulted in a green fluorescent 4-amino-1,8-naphthalimide.(Figure Presented)",

author = "Zhang, {Jun Feng} and Lim, {Chang Su} and Sankarprasad Bhuniya and Bong-Rae Cho and Kim, {Jong Seung}",

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AU - Lim, Chang Su

AU - Bhuniya, Sankarprasad

AU - Cho, Bong-Rae

AU - Kim, Jong Seung

PY - 2011/3/4

Y1 - 2011/3/4

N2 - A naphthalimide-based highly selective colorimetric and ratiometric fluorescent probe for the fluoride ion displayed both one-and two-photon ratiometric changes. Upon reaction with the F- (TBA+ and Na+ salts) anion in CH3CN as well as in aqueous buffer solution, probe 1 shows dramatic color changes from colorless to jade-green and remarkable ratiometric fluorescence enhancements signals. These properties are mechanistically ascribed to a fluoride-triggered Si-O bond cleavage that resulted in a green fluorescent 4-amino-1,8-naphthalimide.(Figure Presented)

AB - A naphthalimide-based highly selective colorimetric and ratiometric fluorescent probe for the fluoride ion displayed both one-and two-photon ratiometric changes. Upon reaction with the F- (TBA+ and Na+ salts) anion in CH3CN as well as in aqueous buffer solution, probe 1 shows dramatic color changes from colorless to jade-green and remarkable ratiometric fluorescence enhancements signals. These properties are mechanistically ascribed to a fluoride-triggered Si-O bond cleavage that resulted in a green fluorescent 4-amino-1,8-naphthalimide.(Figure Presented)

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A highly selective colorimetric and ratiometric two-photon fluorescent probe for fluoride ion detection

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