A new chromium(III)/p-tert-butylcalix[4]arene/alkylaluminum catalyst system for the preparation of low molecular weight polyethylene

Chengzhe Huang, Junghyun Ahn, Soohan Kwon, Jong Seung Kim, Jeongho Lee, Yohan Han, Hyungrok Kim

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

A new chromium(III)/p-tert-butylcalix[4]arene/alkylaluminum catalyst system was applied to assist the ethylene polymerization. The catalyst system was found to be very active for the ethylene polymerization, and gave strictly linear polyethylene, with high crystallinity and low number average molecular weight (Mn) ranging from 910 to 9740, without using molecular hydrogen as a molecular weight reducer. The effects of polymerization parameters such as temperature, ethylene pressure, chromium catalyst concentration, type of alkylaluminum compounds, and Al/Cr molar ratio on the catalytic activity and properties of the polyethylene were investigated. The formation of low molecular weight polyethylene using the chromium(III)/p-tert-butylcalix[4]arene/alkylaluminum catalyst system was explained by the coordination effect of structurally hindered and less electron-donating p-tert-butylcalix[4]arene (LH4) anion ligand.

Original languageEnglish
Pages (from-to)173-181
Number of pages9
JournalApplied Catalysis A: General
Volume258
Issue number2
DOIs
Publication statusPublished - 2004 Feb 20
Externally publishedYes

Fingerprint

Polyethylene
Chromium
Polyethylenes
Molecular weight
Ethylene
Catalysts
Polymerization
Anions
Hydrogen
Catalyst activity
Negative ions
Ligands
Electrons
ethylene
Temperature

Keywords

  • Calixarene
  • Chemical wax
  • Chromium
  • Polyethylene
  • Polymerization

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

A new chromium(III)/p-tert-butylcalix[4]arene/alkylaluminum catalyst system for the preparation of low molecular weight polyethylene. / Huang, Chengzhe; Ahn, Junghyun; Kwon, Soohan; Kim, Jong Seung; Lee, Jeongho; Han, Yohan; Kim, Hyungrok.

In: Applied Catalysis A: General, Vol. 258, No. 2, 20.02.2004, p. 173-181.

Research output: Contribution to journalArticle

Huang, Chengzhe ; Ahn, Junghyun ; Kwon, Soohan ; Kim, Jong Seung ; Lee, Jeongho ; Han, Yohan ; Kim, Hyungrok. / A new chromium(III)/p-tert-butylcalix[4]arene/alkylaluminum catalyst system for the preparation of low molecular weight polyethylene. In: Applied Catalysis A: General. 2004 ; Vol. 258, No. 2. pp. 173-181.
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