A new n-type semiconducting molecule with an asymmetric indenothiophene core for a high-performing non-fullerene type organic solar cell

Young Un Kim, Gi Eun Park, Suna Choi, Dae Hee Lee, Min Ju Cho, Dong Hoon Choi

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Herein, a new asymmetric n-type semiconducting molecule (PhITBD) with an indenothiophene core was designed, synthesized using tethering 2-(benzo[c][1,2,5]-thiadiazol-4-ylmethylene)-malononitrile (BM) as terminal groups, and applied to polymer solar cells (PSCs). The PSCs with asymmetric PhITBD displayed improved power conversion efficiencies (PCE) of 6.57% as compared to those with the symmetric molecule IDT-2BM. The higher PCE value of the PhITBD-based PSC was mainly attributed to the enhanced photovoltaic properties, the Voc, Jsc, FF induced by complementary light absorption (550-600 nm range), morphological improvement, and balanced charge carrier transport in the active layer. Due to the effective morphological control and absorption enhancement, asymmetric structured n-type-conjugated molecules are potential candidates for improving the performance of bulk heterojunction non-fullerene type PSCs.

Original languageEnglish
Pages (from-to)7182-7190
Number of pages9
JournalJournal of Materials Chemistry C
Volume5
Issue number29
DOIs
Publication statusPublished - 2017

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Molecules
Conversion efficiency
Carrier transport
Charge carriers
Light absorption
Heterojunctions
Polymer solar cells
Organic solar cells
dicyanmethane

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

Cite this

A new n-type semiconducting molecule with an asymmetric indenothiophene core for a high-performing non-fullerene type organic solar cell. / Un Kim, Young; Eun Park, Gi; Choi, Suna; Hee Lee, Dae; Ju Cho, Min; Choi, Dong Hoon.

In: Journal of Materials Chemistry C, Vol. 5, No. 29, 2017, p. 7182-7190.

Research output: Contribution to journalArticle

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