A new phosphorescent chemosensor bearing Zn-DPA sites for H 2PO4-

Hye Bin Kim, Yifan Liu, Dayoung Nam, Yinan Li, Sungnam Park, Juyoung Yoon, Myung Ho Hyun

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

A phosphorescence chemosensor bearing an iridium (III) complex as a communicating source and two Zn-DPA units acting as a preorganized binding site for H2PO4- is presented. The phosphorescent chemosensor displayed a selective phosphorescence enhancement with H 2PO4- in aqueous solution and at neutral pH. On the other hand, F-, Cl-, Br-, I-, NO3-, CH3COO-, and ClO 4- did not induce significant changes in phosphorescence. Furthermore, the phosphorescent chemosensor shows selectivity for H 2PO4- over the related phosphate species, such as ATP and pyrophosphate. In addition, there was a distinct lifetime change only for H2PO4-. The association constant was calculated to be 9.68 × 104 M-1 for H 2PO4-.

Original languageEnglish
Pages (from-to)20-24
Number of pages5
JournalDyes and Pigments
Volume106
DOIs
Publication statusPublished - 2014 Jul

Keywords

  • Anion recognition
  • Dihydrogen phosphate sensing
  • Iridium complex
  • Phosphate sensor
  • Phosphorescence chemosensor
  • Zinc complex

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Process Chemistry and Technology

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