A strategy for ultrasensitive and selective detection of methylamine using p-type Cr2O3: Morphological design of sensing materials, control of charge carrier concentrations, and configurational tuning of Au catalysts

Tae Hyung Kim, Ji Wook Yoon, Yun Chan Kang, Faissal Abdel-Hady, A. A. Wazzan, Jong Heun Lee

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

An ultrasensitive and selective trimethylamine (TMA) sensor was fabricated by the urea-assisted uniform loading of Au nanoparticles (∼5 nm) on Cr2O3 yolk-shell spheres prepared by ultrasonic spray pyrolysis. The response (resistance ratio) of the Cr2O3 yolk-shell spheres uniformly loaded with fine Au nanoparticles to 5 ppm TMA was 200.9 at 225 °C, which was significantly higher than those of pure Cr2O3 yolk-shell spheres (24.6) and Cr2O3 yolk-shell spheres loaded with heavily agglomerated Au particles (9.2). The detection limit of Cr2O3 yolk-shell spheres uniformly loaded with Au nanoparticles was as low as 4.3 ppb. The unprecedentedly high TMA response is explained and discussed in relation to the gas-accessible morphology of the yolk-shell spheres, and the catalytic and electronic promotion of the gas sensing reaction by both Cr2O3 and well-dispersed Au nanoparticles.

Original languageEnglish
Pages (from-to)1049-1057
Number of pages9
JournalSensors and Actuators, B: Chemical
Volume240
DOIs
Publication statusPublished - 2017 Mar 1

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Charge carriers
Carrier concentration
charge carriers
Tuning
tuning
catalysts
Catalysts
Nanoparticles
nanoparticles
Gases
Spray pyrolysis
promotion
ureas
gases
Urea
pyrolysis
sprayers
methylamine
ultrasonics
Ultrasonics

Keywords

  • Au nanoparticles
  • CrO
  • Gas sensor
  • Trimethylamine
  • Yolk-shell spheres

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry
  • Electrical and Electronic Engineering

Cite this

A strategy for ultrasensitive and selective detection of methylamine using p-type Cr2O3 : Morphological design of sensing materials, control of charge carrier concentrations, and configurational tuning of Au catalysts. / Kim, Tae Hyung; Yoon, Ji Wook; Kang, Yun Chan; Abdel-Hady, Faissal; Wazzan, A. A.; Lee, Jong Heun.

In: Sensors and Actuators, B: Chemical, Vol. 240, 01.03.2017, p. 1049-1057.

Research output: Contribution to journalArticle

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