TY - JOUR
T1 - A two-photon excited luminescence of water-soluble rhodamine-platinum(II) complex
T2 - Fluorescent probe specific for Hg2+ detection in live cell
AU - Zhang, Jun Feng
AU - Lim, Chang Su
AU - Cho, Bong-Rae
AU - Kim, Jong Seung
N1 - Funding Information:
This work was supported by the CRI project (2010-0000728) (J.S. Kim), NRF grant ( R0A-2010-0018921 ), and Priority Research Centers Program through the NRF funded by the Ministry of Education, Science and Technology (No. 2010-0020209 ) (B.R. Cho). J.F. Zhang acknowledges the “ChunHui Project” Foundation of ministry of education of China , the Foundation of Department of Education of Yunnan Province of China ( 08Y0137 ) and the Foundation of Department of Science and Technology of Yunnan Province of China ( 2008CD104 ). CSL was supported by a BK21 scholarship.
PY - 2010/12/15
Y1 - 2010/12/15
N2 - The first example of cyclometalated platinum(II)-containing rhodamine probe (1) with two-photon induced luminescent properties was synthesized and investigated for mercury detection. A highly selective color change of 1, from light yellow to pink, is observed only in the presence of Hg2+ due to the formation of 1,3,4-oxadiazole ring in 2. This selectivity of Hg 2+ with color changes can be observed easily by the naked-eye. Meanwhile, a remarkable turn-on and selective 20-fold fluorescent enhancement of 1 upon binding with Hg2+ over the other tested metal ions was observed. The water-soluble probe 1 was successfully applied in the visualizing of the site of Hg2+ accumulation as well as estimating of trace amounts of mercury ions in live HeLa cells by two-photon microscopy.
AB - The first example of cyclometalated platinum(II)-containing rhodamine probe (1) with two-photon induced luminescent properties was synthesized and investigated for mercury detection. A highly selective color change of 1, from light yellow to pink, is observed only in the presence of Hg2+ due to the formation of 1,3,4-oxadiazole ring in 2. This selectivity of Hg 2+ with color changes can be observed easily by the naked-eye. Meanwhile, a remarkable turn-on and selective 20-fold fluorescent enhancement of 1 upon binding with Hg2+ over the other tested metal ions was observed. The water-soluble probe 1 was successfully applied in the visualizing of the site of Hg2+ accumulation as well as estimating of trace amounts of mercury ions in live HeLa cells by two-photon microscopy.
KW - Platinum(II) complex
KW - Rhodamine
KW - Two-photon miscroscopy
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U2 - 10.1016/j.talanta.2010.10.016
DO - 10.1016/j.talanta.2010.10.016
M3 - Article
C2 - 21111188
AN - SCOPUS:78649991657
VL - 83
SP - 658
EP - 662
JO - Talanta
JF - Talanta
SN - 0039-9140
IS - 2
ER -