Accurate in-operando study of molten carbonate fuel cell degradation processes -part I

Physiochemical processes individuation

F. Santoni, M. Della Pietra, D. Pumiglia, C. Boigues Muñoz, S. J. McPhail, V. Cigolotti, SukWoo Nam, M. G. Kang, S. P. Yoon

Research output: Contribution to journalArticle

Abstract

This work has the difficult task to deeply study the electrochemical processes that occur inside a 100 cm2 of Molten Carbonate Fuel Cells (MCFC) impedance spectra using the high resolution of Distribution of Relaxation Time (DRT) method. Using this method, it is possible to shed light on the different physicochemical processes occurring within these cells, identifying the characteristic relaxation times by means of an appropriate experimental campaign where temperature and gas compositions in anode and cathode were varied one at a time. The quality of the recorded spectra was verified by Kramers-Kronig relation before applying DRT calculations. In this work, five distinct and separated peaks with different time constants ranging from 0.01 to 500 Hz were identified and associated with physiochemical processes of the cell. Three peaks at high frequency represent the charge transfer processes in anode and cathode active sites. The other two, located at low frequency, are associated with the gas diffusion in the electrodes and to the gas conversion process. This study represents the first application of the DRT approach to this technology allowing to understand the physicochemical origin of the individual polarization processes controlling the cell performance and the degradation. The analysis of degradation processes using the DRT method and the physiochemical processes identification presented in this paper will be shown in part II of this work.

Original languageEnglish
Pages (from-to)343-352
Number of pages10
JournalElectrochimica Acta
Volume291
DOIs
Publication statusPublished - 2018 Nov 20
Externally publishedYes

Fingerprint

Molten carbonate fuel cells (MCFC)
Relaxation time
Degradation
Anodes
Cathodes
Gases
Kramers-Kronig relations
Diffusion in gases
Charge transfer
Polarization
Electrodes
Chemical analysis

Keywords

  • Deconvolution of impedance spectra
  • Degradation processes
  • Distribution of relaxation time
  • Molten carbonate fuel cell
  • Polarization losses

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

Cite this

Santoni, F., Della Pietra, M., Pumiglia, D., Boigues Muñoz, C., McPhail, S. J., Cigolotti, V., ... Yoon, S. P. (2018). Accurate in-operando study of molten carbonate fuel cell degradation processes -part I: Physiochemical processes individuation. Electrochimica Acta, 291, 343-352. https://doi.org/10.1016/j.electacta.2018.08.100

Accurate in-operando study of molten carbonate fuel cell degradation processes -part I : Physiochemical processes individuation. / Santoni, F.; Della Pietra, M.; Pumiglia, D.; Boigues Muñoz, C.; McPhail, S. J.; Cigolotti, V.; Nam, SukWoo; Kang, M. G.; Yoon, S. P.

In: Electrochimica Acta, Vol. 291, 20.11.2018, p. 343-352.

Research output: Contribution to journalArticle

Santoni, F, Della Pietra, M, Pumiglia, D, Boigues Muñoz, C, McPhail, SJ, Cigolotti, V, Nam, S, Kang, MG & Yoon, SP 2018, 'Accurate in-operando study of molten carbonate fuel cell degradation processes -part I: Physiochemical processes individuation', Electrochimica Acta, vol. 291, pp. 343-352. https://doi.org/10.1016/j.electacta.2018.08.100
Santoni, F. ; Della Pietra, M. ; Pumiglia, D. ; Boigues Muñoz, C. ; McPhail, S. J. ; Cigolotti, V. ; Nam, SukWoo ; Kang, M. G. ; Yoon, S. P. / Accurate in-operando study of molten carbonate fuel cell degradation processes -part I : Physiochemical processes individuation. In: Electrochimica Acta. 2018 ; Vol. 291. pp. 343-352.
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