Ag-doped manganese oxide catalyst for gasoline particulate filters: Effect of crystal phase on soot oxidation activity

Min June Kim, Eun Jun Lee, Eunwon Lee, Do Heui Kim, Dae Won Lee, Chang Hwan Kim, Kwan Young Lee

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Manganese oxide catalysts were synthesized by a hydrothermal method, and silver was doped to promote active oxygen generation. As the calcination temperature increased, the crystal phases of manganese oxide were changed into Mn2O3 from cryptomelane (KMn8O16). In the soot oxidation experiments under GPF conditions, Mn2O3 exhibited higher soot oxidation activities than cryptomelane. To identify the reason for soot oxidation activities, general characterization methods related to the redox properties of the catalyst were performed, including XPS, O2-TPD, H2 TPR, and Soot TPR. However, the soot oxidation activities were not correlated with the characterization results because cryptomelane had higher reducibility compared to Mn2O3. Therefore, cycled H2-TPR, which reflects the redox mechanism of the catalyst in the oxidation reaction, was performed. As a result, Mn2O3 readily regenerated active oxygen compared with cryptomelane, which resulted in higher soot oxidation activity under GPF conditions. In this study, the main factor in the soot oxidation activity of manganese oxide was unveiled, and the result is believed to be helpful in further study of soot oxidation using manganese oxide catalysts.

Original languageEnglish
Article number151041
JournalApplied Surface Science
Volume569
DOIs
Publication statusPublished - 2021 Dec 15

Keywords

  • Active oxygen regeneration
  • Ag-doped manganese oxide
  • Crystal phase effect
  • Gasoline particulate filter catalyst
  • Soot oxidation

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Physics and Astronomy(all)
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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