All-in-One Beaker Method for Large-Scale Production of Metal Oxide Hollow Nanospheres Using Nanoscale Kirkendall Diffusion

Jung Sang Cho, Yun Chan Kang

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A simple and easily scalable process for the formation of metal oxide hollow nanospheres using nanoscale Kirkendall diffusion called the "all-in-one beaker method" is introduced. The Fe2O3, SnO2, NiO, and Co3O4 hollow nanospheres are successfully prepared by the all-in-one beaker method. The detailed formation mechanism of aggregate-free hematite hollow nanospheres is studied. Dimethylformamide solution containing Fe acetate, polyacrylonitrile (PAN), and polystyrene (PS) transforms into aggregate-free Fe2O3 hollow nanospheres. The porous structure formed by the combustion of PS provides a good pathway for the reducing gas. The carbon matrix formed from PAN acts as a barrier, which can prevent the aggregation of metallic Fe nanopowders by surrounding each particle. The Fe-C bulk material formed as an intermediate product transforms into aggregate-free Fe2O3 hollow nanospheres by the nanoscale Kirkendall diffusion process. The mean size and shell thickness of the hollow Fe2O3 nanospheres measured from the TEM images are 52 and 9 nm, respectively. The discharge capacities of the Fe2O3 nanopowders with hollow and dense structures and the bulk material for the 200th cycle at a current density of 0.5 A g-1 are 1012, 498, and 637 mA h g-1, respectively, and their capacity retentions calculated compared to those in the second cycles are 92, 45, and 59%, respectively. Additionally, Fe2O3 hollow nanospheres cycled at 1 A g-1 after 1000 cycles showed a high discharge capacity of 871 mA h g-1 (capacity retention was 80% from the second cycle). The Fe2O3, SnO2, NiO, and Co3O4 hollow nanospheres show excellent cycling performances for lithium-ion storage because they have a high contact area with the liquid electrolyte and space for accommodating a huge volume change during cycling.

Original languageEnglish
Pages (from-to)3800-3809
Number of pages10
JournalACS Applied Materials and Interfaces
Volume8
Issue number6
DOIs
Publication statusPublished - 2016 Feb 24

Fingerprint

Nanospheres
Oxides
Metals
Polyacrylonitriles
Polystyrenes
Dimethylformamide
Hematite
Lithium
Contacts (fluid mechanics)
Electrolytes
Acetates
Current density
Carbon
Agglomeration
Gases
Ions
Transmission electron microscopy
Liquids

Keywords

  • anode material
  • hollow nanosphere
  • iron oxide
  • Kirkendall diffusion
  • lithium-ion battery

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

All-in-One Beaker Method for Large-Scale Production of Metal Oxide Hollow Nanospheres Using Nanoscale Kirkendall Diffusion. / Cho, Jung Sang; Kang, Yun Chan.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 6, 24.02.2016, p. 3800-3809.

Research output: Contribution to journalArticle

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N2 - A simple and easily scalable process for the formation of metal oxide hollow nanospheres using nanoscale Kirkendall diffusion called the "all-in-one beaker method" is introduced. The Fe2O3, SnO2, NiO, and Co3O4 hollow nanospheres are successfully prepared by the all-in-one beaker method. The detailed formation mechanism of aggregate-free hematite hollow nanospheres is studied. Dimethylformamide solution containing Fe acetate, polyacrylonitrile (PAN), and polystyrene (PS) transforms into aggregate-free Fe2O3 hollow nanospheres. The porous structure formed by the combustion of PS provides a good pathway for the reducing gas. The carbon matrix formed from PAN acts as a barrier, which can prevent the aggregation of metallic Fe nanopowders by surrounding each particle. The Fe-C bulk material formed as an intermediate product transforms into aggregate-free Fe2O3 hollow nanospheres by the nanoscale Kirkendall diffusion process. The mean size and shell thickness of the hollow Fe2O3 nanospheres measured from the TEM images are 52 and 9 nm, respectively. The discharge capacities of the Fe2O3 nanopowders with hollow and dense structures and the bulk material for the 200th cycle at a current density of 0.5 A g-1 are 1012, 498, and 637 mA h g-1, respectively, and their capacity retentions calculated compared to those in the second cycles are 92, 45, and 59%, respectively. Additionally, Fe2O3 hollow nanospheres cycled at 1 A g-1 after 1000 cycles showed a high discharge capacity of 871 mA h g-1 (capacity retention was 80% from the second cycle). The Fe2O3, SnO2, NiO, and Co3O4 hollow nanospheres show excellent cycling performances for lithium-ion storage because they have a high contact area with the liquid electrolyte and space for accommodating a huge volume change during cycling.

AB - A simple and easily scalable process for the formation of metal oxide hollow nanospheres using nanoscale Kirkendall diffusion called the "all-in-one beaker method" is introduced. The Fe2O3, SnO2, NiO, and Co3O4 hollow nanospheres are successfully prepared by the all-in-one beaker method. The detailed formation mechanism of aggregate-free hematite hollow nanospheres is studied. Dimethylformamide solution containing Fe acetate, polyacrylonitrile (PAN), and polystyrene (PS) transforms into aggregate-free Fe2O3 hollow nanospheres. The porous structure formed by the combustion of PS provides a good pathway for the reducing gas. The carbon matrix formed from PAN acts as a barrier, which can prevent the aggregation of metallic Fe nanopowders by surrounding each particle. The Fe-C bulk material formed as an intermediate product transforms into aggregate-free Fe2O3 hollow nanospheres by the nanoscale Kirkendall diffusion process. The mean size and shell thickness of the hollow Fe2O3 nanospheres measured from the TEM images are 52 and 9 nm, respectively. The discharge capacities of the Fe2O3 nanopowders with hollow and dense structures and the bulk material for the 200th cycle at a current density of 0.5 A g-1 are 1012, 498, and 637 mA h g-1, respectively, and their capacity retentions calculated compared to those in the second cycles are 92, 45, and 59%, respectively. Additionally, Fe2O3 hollow nanospheres cycled at 1 A g-1 after 1000 cycles showed a high discharge capacity of 871 mA h g-1 (capacity retention was 80% from the second cycle). The Fe2O3, SnO2, NiO, and Co3O4 hollow nanospheres show excellent cycling performances for lithium-ion storage because they have a high contact area with the liquid electrolyte and space for accommodating a huge volume change during cycling.

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