Altering the coffee-ring effect by adding a surfactant-like viscous polymer solution

Changdeok Seo, Daeho Jang, Jongjin Chae, Sehyun Shin

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A uniform deposition of the suspended particles in an evaporating droplet is necessary in many research fields. Such deposition is difficult to achieve, because the coffee-ring effect dominates the internal flow in a droplet. The present study adopts a biocompatible, surfactant-like polymer (Polyethylene glycol, PEG) to break the coffee-ring effect and obtain a relatively uniform deposition of the microparticles with yielding multi-ring pattern over a droplet area. Movements of the suspended particles in evaporating droplets and deposition patterns of them on a glass substrate were analyzed with microscopic images and video files. The PEG in the droplets successfully altered the coffee-ring effect because of the surface tension variation, which induced a centripetal Marangoni flow. Balancing these two phenomena apparently generated the Marangoni vortex. For PEG solution droplets, the pinning-depinning process during evaporation was periodically repeated and multiple rings were regularly formed. In conclusion, adding a surfactant-like viscous polymer in a droplet could provide a uniform coating of suspended particles, such as cells and various biomaterials, which would be essentially required for droplet assays of biomedical applications.

Original languageEnglish
Article number500
JournalScientific Reports
Volume7
Issue number1
DOIs
Publication statusPublished - 2017 Dec 1

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Coffee
Polymer solutions
Surface active agents
Polyethylene glycols
Polymers
Biomaterials
Surface tension
Assays
Evaporation
Vortex flow
Glass
Coatings
Substrates

ASJC Scopus subject areas

  • General

Cite this

Altering the coffee-ring effect by adding a surfactant-like viscous polymer solution. / Seo, Changdeok; Jang, Daeho; Chae, Jongjin; Shin, Sehyun.

In: Scientific Reports, Vol. 7, No. 1, 500, 01.12.2017.

Research output: Contribution to journalArticle

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