Abstract
The aim of this study was to investigate the scratch characteristics of automotive clearcoats based on an acrylic polyol resin, with butylated melamine and silane modified blocked isocyanates, using car-wash and nano-scratch tests.To scrutinize the effect of silane modified blocked isocyanate on the chemical and mechanical properties of clearcoats, with respect to changes in the crosslinking networks inside the clearcoats due to the curing reaction, dynamic mechanical analysis (DMA) and FT-IR analysis were performed. The scratch behaviors were analyzed via Amtec-Kistler car-wash and nano-scratch tests, accompanied with scratch images simultaneously visualized using atomic force microscopy (AFM) and scanning electron microscopy (SEM). The basic properties of various automotive clearcoats such as impact resistance, pencil hardness, solvent resistance, and stone-chip resistance, were also compared. The results showed that a close correlation existed between the scratch resistance data obtained from the car-wash and nano-scratch tests for clearcoats made from acrylic polyol resin, with melamine and silane modified blocked isocyanates. Also, all the mechanical properties, including scratch resistance, noticeably improved due to the increased crosslinking networks via the formation of urethane bonds, when the portion of silane modified blocked isocyanates was increased. This was verified from the surface profiles and images of the scratched clearcoats captured using AFM and SEM.
| Original language | English |
|---|---|
| Pages (from-to) | 192-203 |
| Number of pages | 12 |
| Journal | Progress in Organic Coatings |
| Volume | 74 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2012 May 1 |
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Keywords
- Automotive clearcoat
- Car-wash
- Mechanical properties
- Nano-scratch
- Scratch resistance
- Silane modified blocked isocyanate
ASJC Scopus subject areas
- Organic Chemistry
- Surfaces, Coatings and Films
- Materials Chemistry
- Chemical Engineering(all)
Cite this
Analysis of scratch characteristics of automotive clearcoats containing silane modified blocked isocyanates via carwash and nano-scratch tests. / Noh, Seung M.; Lee, Jae W.; Nam, Joon H.; Park, Jong M.; Jung, Hyun Wook.
In: Progress in Organic Coatings, Vol. 74, No. 1, 01.05.2012, p. 192-203.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Analysis of scratch characteristics of automotive clearcoats containing silane modified blocked isocyanates via carwash and nano-scratch tests
AU - Noh, Seung M.
AU - Lee, Jae W.
AU - Nam, Joon H.
AU - Park, Jong M.
AU - Jung, Hyun Wook
PY - 2012/5/1
Y1 - 2012/5/1
N2 - The aim of this study was to investigate the scratch characteristics of automotive clearcoats based on an acrylic polyol resin, with butylated melamine and silane modified blocked isocyanates, using car-wash and nano-scratch tests.To scrutinize the effect of silane modified blocked isocyanate on the chemical and mechanical properties of clearcoats, with respect to changes in the crosslinking networks inside the clearcoats due to the curing reaction, dynamic mechanical analysis (DMA) and FT-IR analysis were performed. The scratch behaviors were analyzed via Amtec-Kistler car-wash and nano-scratch tests, accompanied with scratch images simultaneously visualized using atomic force microscopy (AFM) and scanning electron microscopy (SEM). The basic properties of various automotive clearcoats such as impact resistance, pencil hardness, solvent resistance, and stone-chip resistance, were also compared. The results showed that a close correlation existed between the scratch resistance data obtained from the car-wash and nano-scratch tests for clearcoats made from acrylic polyol resin, with melamine and silane modified blocked isocyanates. Also, all the mechanical properties, including scratch resistance, noticeably improved due to the increased crosslinking networks via the formation of urethane bonds, when the portion of silane modified blocked isocyanates was increased. This was verified from the surface profiles and images of the scratched clearcoats captured using AFM and SEM.
AB - The aim of this study was to investigate the scratch characteristics of automotive clearcoats based on an acrylic polyol resin, with butylated melamine and silane modified blocked isocyanates, using car-wash and nano-scratch tests.To scrutinize the effect of silane modified blocked isocyanate on the chemical and mechanical properties of clearcoats, with respect to changes in the crosslinking networks inside the clearcoats due to the curing reaction, dynamic mechanical analysis (DMA) and FT-IR analysis were performed. The scratch behaviors were analyzed via Amtec-Kistler car-wash and nano-scratch tests, accompanied with scratch images simultaneously visualized using atomic force microscopy (AFM) and scanning electron microscopy (SEM). The basic properties of various automotive clearcoats such as impact resistance, pencil hardness, solvent resistance, and stone-chip resistance, were also compared. The results showed that a close correlation existed between the scratch resistance data obtained from the car-wash and nano-scratch tests for clearcoats made from acrylic polyol resin, with melamine and silane modified blocked isocyanates. Also, all the mechanical properties, including scratch resistance, noticeably improved due to the increased crosslinking networks via the formation of urethane bonds, when the portion of silane modified blocked isocyanates was increased. This was verified from the surface profiles and images of the scratched clearcoats captured using AFM and SEM.
KW - Automotive clearcoat
KW - Car-wash
KW - Mechanical properties
KW - Nano-scratch
KW - Scratch resistance
KW - Silane modified blocked isocyanate
UR - http://www.scopus.com/inward/record.url?scp=84857995201&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84857995201&partnerID=8YFLogxK
U2 - 10.1016/j.porgcoat.2011.12.009
DO - 10.1016/j.porgcoat.2011.12.009
M3 - Article
AN - SCOPUS:84857995201
VL - 74
SP - 192
EP - 203
JO - Progress in Organic Coatings
JF - Progress in Organic Coatings
SN - 0300-9440
IS - 1
ER -