Annealing-free high-mobility diketopyrrolopyrrole-benzodithiophene copolymer for organic thin film transistors

Dae Hee Lee; Jicheol Shin; Tae Wan Lee; Min Ju Cho; Dong Hoon Choi

doi:10.1080/15421406.2014.933304

Annealing-free high-mobility diketopyrrolopyrrole-benzodithiophene copolymer for organic thin film transistors

Dae Hee Lee, Jicheol Shin, Tae Wan Lee, Min Ju Cho, Dong Hoon Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Diketopyrrolopyrrole (DPP)-based conjugated polymer (P(DPP-BDT)) containing benzodithiophene (BDT) was successfully synthesized via Stille coupling reaction. The synthesized polymer shows good solubility in common organic solvents and good selffilm- forming properties. The electrical properties of the polymer were evaluated in organic thin film transistors (OTFTs). The TFT made of pristine P(DPP-BDT) film exhibits good carrier mobility of 0.38∼0.40 cm² V^-1 s^-1 (I_on/off = 10⁶, V_th =-9 V), which is close to the mobility of TFT made of the thermally annealed film.

Original language	English
Pages (from-to)	97-103
Number of pages	7
Journal	Molecular Crystals and Liquid Crystals
Volume	598
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2014.933304
Publication status	Published - 2014 Jul 24

Keywords

Benzodithiophene
Conjugated polymer
Diketopyrrolopyrrole
Mobility
Organic thin film transistor
Semiconductor

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1080/15421406.2014.933304

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@article{cd928ce0d70141cbb870e627eb714984,

title = "Annealing-free high-mobility diketopyrrolopyrrole-benzodithiophene copolymer for organic thin film transistors",

abstract = "Diketopyrrolopyrrole (DPP)-based conjugated polymer (P(DPP-BDT)) containing benzodithiophene (BDT) was successfully synthesized via Stille coupling reaction. The synthesized polymer shows good solubility in common organic solvents and good selffilm- forming properties. The electrical properties of the polymer were evaluated in organic thin film transistors (OTFTs). The TFT made of pristine P(DPP-BDT) film exhibits good carrier mobility of 0.38∼0.40 cm2 V-1 s-1 (Ion/off = 106, Vth =-9 V), which is close to the mobility of TFT made of the thermally annealed film.",

keywords = "Benzodithiophene, Conjugated polymer, Diketopyrrolopyrrole, Mobility, Organic thin film transistor, Semiconductor",

author = "Lee, {Dae Hee} and Jicheol Shin and Lee, {Tae Wan} and Cho, {Min Ju} and Choi, {Dong Hoon}",

note = "Funding Information: This research was supported by National Research Foundation of Korea (NRF2012R1A2A1A01008797 & 20110026418) and by Key Research Institute Program through the NRF funded by the Ministry of Education, Science and Technology (NRF20100020209). Publisher Copyright: {\textcopyright} Taylor & Francis Group, LLC.",

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doi = "10.1080/15421406.2014.933304",

language = "English",

volume = "598",

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T1 - Annealing-free high-mobility diketopyrrolopyrrole-benzodithiophene copolymer for organic thin film transistors

AU - Lee, Dae Hee

AU - Shin, Jicheol

AU - Lee, Tae Wan

AU - Cho, Min Ju

AU - Choi, Dong Hoon

N1 - Funding Information: This research was supported by National Research Foundation of Korea (NRF2012R1A2A1A01008797 & 20110026418) and by Key Research Institute Program through the NRF funded by the Ministry of Education, Science and Technology (NRF20100020209). Publisher Copyright: © Taylor & Francis Group, LLC.

PY - 2014/7/24

Y1 - 2014/7/24

N2 - Diketopyrrolopyrrole (DPP)-based conjugated polymer (P(DPP-BDT)) containing benzodithiophene (BDT) was successfully synthesized via Stille coupling reaction. The synthesized polymer shows good solubility in common organic solvents and good selffilm- forming properties. The electrical properties of the polymer were evaluated in organic thin film transistors (OTFTs). The TFT made of pristine P(DPP-BDT) film exhibits good carrier mobility of 0.38∼0.40 cm2 V-1 s-1 (Ion/off = 106, Vth =-9 V), which is close to the mobility of TFT made of the thermally annealed film.

AB - Diketopyrrolopyrrole (DPP)-based conjugated polymer (P(DPP-BDT)) containing benzodithiophene (BDT) was successfully synthesized via Stille coupling reaction. The synthesized polymer shows good solubility in common organic solvents and good selffilm- forming properties. The electrical properties of the polymer were evaluated in organic thin film transistors (OTFTs). The TFT made of pristine P(DPP-BDT) film exhibits good carrier mobility of 0.38∼0.40 cm2 V-1 s-1 (Ion/off = 106, Vth =-9 V), which is close to the mobility of TFT made of the thermally annealed film.

KW - Benzodithiophene

KW - Conjugated polymer

KW - Diketopyrrolopyrrole

KW - Mobility

KW - Organic thin film transistor

KW - Semiconductor

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U2 - 10.1080/15421406.2014.933304

DO - 10.1080/15421406.2014.933304

M3 - Article

AN - SCOPUS:84945181796

SN - 1542-1406

VL - 598

SP - 97

EP - 103

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Annealing-free high-mobility diketopyrrolopyrrole-benzodithiophene copolymer for organic thin film transistors

Abstract

Keywords

ASJC Scopus subject areas

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