Application of excited-state intramolecular proton transfer (ESIPT) principle to functional polymeric materials

Sanghyuk Park; Sehoon Kim; Jangwon Seo; Soo Young Park

doi:10.1007/BF03218534

Application of excited-state intramolecular proton transfer (ESIPT) principle to functional polymeric materials

Sanghyuk Park, Sehoon Kim, Jangwon Seo, Soo Young Park

KU-KIST Graduate School of Converging Science and Technology

Research output: Contribution to journal › Review article › peer-review

49 Citations (Scopus)

Abstract

Synthesis and properties of novel excited-state intramolecular proton transfer (ESIPT) materials, recently developed in our group, are described. Highly efficient ESIPT reaction, achieved in polyquinolines, polybenzoxazoles, and oxadiazole and imidazole derivatives possessing an intramolecular tautomerizable hydrogen bond, has been investigated theoretically and experimentally. It is demonstrated that unique properties arising from the ESIPT process (large Stokes' shift, no self-absorption, and easy population inversion, etc.) make it possible to produce advanced polymer devices for lasing, optical storage, and electroluminescence.

Original language	English
Pages (from-to)	385-395
Number of pages	11
Journal	Macromolecular Research
Volume	16
Issue number	5
DOIs	https://doi.org/10.1007/BF03218534
Publication status	Published - 2008 Jul

Keywords

Amplified spontaneous emission
Electroluminescence
Excited-state intramolecular proton transfer
Fluorescence
Optical patterning

ASJC Scopus subject areas

Chemical Engineering(all)
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1007/BF03218534

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title = "Application of excited-state intramolecular proton transfer (ESIPT) principle to functional polymeric materials",

abstract = "Synthesis and properties of novel excited-state intramolecular proton transfer (ESIPT) materials, recently developed in our group, are described. Highly efficient ESIPT reaction, achieved in polyquinolines, polybenzoxazoles, and oxadiazole and imidazole derivatives possessing an intramolecular tautomerizable hydrogen bond, has been investigated theoretically and experimentally. It is demonstrated that unique properties arising from the ESIPT process (large Stokes' shift, no self-absorption, and easy population inversion, etc.) make it possible to produce advanced polymer devices for lasing, optical storage, and electroluminescence.",

keywords = "Amplified spontaneous emission, Electroluminescence, Excited-state intramolecular proton transfer, Fluorescence, Optical patterning",

author = "Sanghyuk Park and Sehoon Kim and Jangwon Seo and Park, {Soo Young}",

year = "2008",

month = jul,

doi = "10.1007/BF03218534",

language = "English",

volume = "16",

pages = "385--395",

journal = "Macromolecular Research",

issn = "1598-5032",

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TY - JOUR

T1 - Application of excited-state intramolecular proton transfer (ESIPT) principle to functional polymeric materials

AU - Park, Sanghyuk

AU - Kim, Sehoon

AU - Seo, Jangwon

AU - Park, Soo Young

PY - 2008/7

Y1 - 2008/7

N2 - Synthesis and properties of novel excited-state intramolecular proton transfer (ESIPT) materials, recently developed in our group, are described. Highly efficient ESIPT reaction, achieved in polyquinolines, polybenzoxazoles, and oxadiazole and imidazole derivatives possessing an intramolecular tautomerizable hydrogen bond, has been investigated theoretically and experimentally. It is demonstrated that unique properties arising from the ESIPT process (large Stokes' shift, no self-absorption, and easy population inversion, etc.) make it possible to produce advanced polymer devices for lasing, optical storage, and electroluminescence.

AB - Synthesis and properties of novel excited-state intramolecular proton transfer (ESIPT) materials, recently developed in our group, are described. Highly efficient ESIPT reaction, achieved in polyquinolines, polybenzoxazoles, and oxadiazole and imidazole derivatives possessing an intramolecular tautomerizable hydrogen bond, has been investigated theoretically and experimentally. It is demonstrated that unique properties arising from the ESIPT process (large Stokes' shift, no self-absorption, and easy population inversion, etc.) make it possible to produce advanced polymer devices for lasing, optical storage, and electroluminescence.

KW - Amplified spontaneous emission

KW - Electroluminescence

KW - Excited-state intramolecular proton transfer

KW - Fluorescence

KW - Optical patterning

UR - http://www.scopus.com/inward/record.url?scp=49049117319&partnerID=8YFLogxK

U2 - 10.1007/BF03218534

DO - 10.1007/BF03218534

M3 - Review article

AN - SCOPUS:49049117319

SN - 1598-5032

VL - 16

SP - 385

EP - 395

JO - Macromolecular Research

JF - Macromolecular Research

IS - 5

ER -

Application of excited-state intramolecular proton transfer (ESIPT) principle to functional polymeric materials

Abstract

Keywords

ASJC Scopus subject areas

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