Ash-free coal as fuel for direct carbon fuel cell

Injae Lee, Sunmi Jin, Donghyuk Chun, Hokyung Choi, Sihyun Lee, Ki Bong Lee, Jiho Yoo

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16 Citations (Scopus)

Abstract

This work describes the performance of the direct carbon fuel cell (DCFC) fuelled by ash-free coal. Employing coal in the DCFC might be problematic, mainly because of the ash deposition after the cell reactions. In the study, the carbonaceous ash-free component of coal is obtained, which is then evaluated as the DCFC fuel and compared with raw coal, active carbon, carbon black, and graphite. The electrolyte-supported SOFC structure is adapted to build the DCFC. The DCFC based on the ash-free coal fuel exhibits good performance with regard to the maximum power density, day-by-day measurements, and durability at continuous run. When the carbon fuels are internally gasified to H2 and CO, the power density is generally much improved, compared to N2 pyrolysis environment. The power generation is most likely related to the concentration of pyrolyzed gases as well as the electrochemical reactivity of the solid carbon.

Original languageEnglish
Pages (from-to)1010-1018
Number of pages9
JournalScience China Chemistry
Volume57
Issue number7
DOIs
Publication statusPublished - 2014 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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  • Cite this

    Lee, I., Jin, S., Chun, D., Choi, H., Lee, S., Lee, K. B., & Yoo, J. (2014). Ash-free coal as fuel for direct carbon fuel cell. Science China Chemistry, 57(7), 1010-1018. https://doi.org/10.1007/s11426-014-5105-z