Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature

Eun Kim Dong, Su Kim In, Virginie Ratovelomanana-Vidal, Jean Pierre Genêt, Nakcheol Jeong

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

(Chemical Equation Presented) An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20°C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.

Original languageEnglish
Pages (from-to)7985-7989
Number of pages5
JournalJournal of Organic Chemistry
Volume73
Issue number20
DOIs
Publication statusPublished - 2008 Oct 17

ASJC Scopus subject areas

  • Organic Chemistry

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