Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature

Eun Kim Dong, Su Kim In, Virginie Ratovelomanana-Vidal, Jean Pierre Genêt, Nakcheol Jeong

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

(Chemical Equation Presented) An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20°C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.

Original languageEnglish
Pages (from-to)7985-7989
Number of pages5
JournalJournal of Organic Chemistry
Volume73
Issue number20
DOIs
Publication statusPublished - 2008 Oct 17

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Partial Pressure
Carbon Monoxide
Bearings (structural)
Ligands
Catalysts
Temperature
Enantioselectivity
Partial pressure
2-naphthol BINAP

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature. / Dong, Eun Kim; In, Su Kim; Ratovelomanana-Vidal, Virginie; Genêt, Jean Pierre; Jeong, Nakcheol.

In: Journal of Organic Chemistry, Vol. 73, No. 20, 17.10.2008, p. 7985-7989.

Research output: Contribution to journalArticle

Dong, Eun Kim ; In, Su Kim ; Ratovelomanana-Vidal, Virginie ; Genêt, Jean Pierre ; Jeong, Nakcheol. / Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature. In: Journal of Organic Chemistry. 2008 ; Vol. 73, No. 20. pp. 7985-7989.
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