@article{d6b110e475394901bf10689c3d9e6f9b,
title = "Asymmetric Pauson-Khand-type reactions of 1,6-enynes using formaldehyde as a carbonyl source by cooperative dual rhodium catalysis",
abstract = "A dual neutral-cationic rhodium(I)-catalyzed Pauson-Khand-type reaction using formaldehyde as a carbonyl source is described. The simultaneous use of neutral rhodium(I) and cationic rhodium(I) complexes is required for efficient cooperative catalysis, which involves the neutral rhodium(I)-catalyzed decarbonylation of formaldehyde and the cationic rhodium(I)-catalyzed cyclocarbonylation of 1,6-enynes using the resulting carbonyl moiety.",
keywords = "Asymmetric Pauson-Khand reaction, Decarbonylation, Dual catalysis, Enyne, Formaldehyde",
author = "Takuma Furusawa and Tsumoru Morimoto and Keiichi Ikeda and Hiroki Tanimoto and Yasuhiro Nishiyama and Kiyomi Kakiuchi and Nakcheol Jeong",
note = "Funding Information: This work was supported partly by Grants-in-Aid for Scientific Research on Innovative Area {\textquoteleft}Molecular Activation Directed toward Straightforward Synthesis{\textquoteright} from the Ministry of Education, Culture, Sports, Science and Technology, Japan (No. 25105737 ). We thank Ms. Yoshiko Nishikawa and Mr. Kazuo Fukuda for the HRMS measurements. Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd. All rights reserved.",
year = "2015",
month = feb,
day = "4",
doi = "10.1016/j.tet.2014.12.038",
language = "English",
volume = "71",
pages = "875--881",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "5",
}