Abstract
A dual neutral-cationic rhodium(I)-catalyzed Pauson-Khand-type reaction using formaldehyde as a carbonyl source is described. The simultaneous use of neutral rhodium(I) and cationic rhodium(I) complexes is required for efficient cooperative catalysis, which involves the neutral rhodium(I)-catalyzed decarbonylation of formaldehyde and the cationic rhodium(I)-catalyzed cyclocarbonylation of 1,6-enynes using the resulting carbonyl moiety.
| Original language | English |
|---|---|
| Pages (from-to) | 875-881 |
| Number of pages | 7 |
| Journal | Tetrahedron |
| Volume | 71 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2015 Feb 4 |
Keywords
- Asymmetric Pauson-Khand reaction
- Decarbonylation
- Dual catalysis
- Enyne
- Formaldehyde
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
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Furusawa, T., Morimoto, T., Ikeda, K., Tanimoto, H., Nishiyama, Y., Kakiuchi, K., & Jeong, N. (2015). Asymmetric Pauson-Khand-type reactions of 1,6-enynes using formaldehyde as a carbonyl source by cooperative dual rhodium catalysis. Tetrahedron, 71(5), 875-881. https://doi.org/10.1016/j.tet.2014.12.038