Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes

Jhinhwan Lee, H. Kim, Se-Jong Kahng, G. Kim, Y. W. Son, J. Ihm, H. Kato, Z. W. Wang, T. Okazaki, H. Shinohara, Young Kuk

Research output: Contribution to journalArticle

400 Citations (Scopus)

Abstract

Motivated by the technical and economic difficulties in further miniaturizing silicon-based transistors with the present fabrication technologies, there is a strong effort to develop alternative electronic devices, based, for example, on single molecules. Recently, carbon nanotubes have been successfully used for nanometre-sized devices such as diodes, transistors, and random access memory cells. Such nanotube devices are usually very long compared to silicon-based transistors. Here we report a method for dividing a semiconductor nanotube into multiple quantum dots with lengths of about 10 nm by inserting Gd@C82 endohedral fullerenes. The spatial modulation of the nanotube electronic bandgap is observed with a low-temperature scanning tunnelling microscope. We find that a bandgap of ∼0.5 eV is narrowed down to ∼0.1 eV at sites where endohedral metallofullerenes are inserted. This change in bandgap can be explained by local elastic strain and charge transfer at metallofullerene sites. This technique for fabricating an array of quantum dots could be used for nano-electronics and nano-optoelectronics.

Original languageEnglish
Pages (from-to)1005-1008
Number of pages4
JournalNature
Volume415
Issue number6875
DOIs
Publication statusPublished - 2002 Feb 28
Externally publishedYes

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Nanotubes
Carbon Nanotubes
Quantum Dots
Silicon
Equipment and Supplies
Fullerenes
Semiconductors
Economics
Technology
Temperature

ASJC Scopus subject areas

  • General

Cite this

Lee, J., Kim, H., Kahng, S-J., Kim, G., Son, Y. W., Ihm, J., ... Kuk, Y. (2002). Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes. Nature, 415(6875), 1005-1008. https://doi.org/10.1038/4151005a

Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes. / Lee, Jhinhwan; Kim, H.; Kahng, Se-Jong; Kim, G.; Son, Y. W.; Ihm, J.; Kato, H.; Wang, Z. W.; Okazaki, T.; Shinohara, H.; Kuk, Young.

In: Nature, Vol. 415, No. 6875, 28.02.2002, p. 1005-1008.

Research output: Contribution to journalArticle

Lee, J, Kim, H, Kahng, S-J, Kim, G, Son, YW, Ihm, J, Kato, H, Wang, ZW, Okazaki, T, Shinohara, H & Kuk, Y 2002, 'Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes', Nature, vol. 415, no. 6875, pp. 1005-1008. https://doi.org/10.1038/4151005a
Lee, Jhinhwan ; Kim, H. ; Kahng, Se-Jong ; Kim, G. ; Son, Y. W. ; Ihm, J. ; Kato, H. ; Wang, Z. W. ; Okazaki, T. ; Shinohara, H. ; Kuk, Young. / Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes. In: Nature. 2002 ; Vol. 415, No. 6875. pp. 1005-1008.
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