Bendable Solar Cells from Stable, Flexible, and Transparent Conducting Electrodes Fabricated Using a Nitrogen-Doped Ultrathin Copper Film

Guoqing Zhao, Soo Min Kim, Sang Geul Lee, Tae Sung Bae, Chae Won Mun, Sunghun Lee, Huashun Yu, Gun Hwan Lee, Haeseok Lee, Myungkwan Song, Jungheum Yun

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Copper has attracted significant interests as an abundant and low-cost alternative material for flexible transparent conducting electrodes (FTCEs). However, Cu-based FTCEs still present unsolved technical issues, such as their inferior light transmittance and oxidation durability compared to conventional indium tin oxide (ITO) and silver metal electrodes. This study reports a novel technique for fabricating highly efficient FTCEs composed of a copper ultrathin film sandwiched between zinc oxides, with enhanced transparency and antioxidation performances. A completely continuous and smooth copper ultrathin film is fabricated by a simple room-temperature reactive sputtering process involving controlled nitrogen doping (<1%) due to a dramatic improvement in the wettability of copper on zinc oxide surfaces. The electrode based on the nitrogen-doped copper film exhibits an optimized average transmittance of 84% over a spectral range of 380 −1000 nm and a sheet resistance lower than 20 Ω sq −1 , with no electrical degradation after exposure to strong oxidation conditions for 760 h. Remarkably, a flexible organic solar cell based on the present Cu-based FTCE achieves a power conversion efficiency of 7.1%, clearly exceeding that (6.6%) of solar cells utilizing the conventional ITO film, and this excellent performance is maintained even in almost completely bent configurations.

Original languageEnglish
Pages (from-to)4180-4191
Number of pages12
JournalAdvanced Functional Materials
Volume26
Issue number23
DOIs
Publication statusPublished - 2016 Jun 20

Fingerprint

Copper
Solar cells
Nitrogen
solar cells
nitrogen
conduction
copper
Electrodes
electrodes
Zinc Oxide
Ultrathin films
Zinc oxide
Tin oxides
zinc oxides
indium oxides
Indium
tin oxides
transmittance
Oxidation
oxidation

Keywords

  • copper
  • flexible transparent conducting electrode
  • organic solar cell
  • polymer substrate
  • thin film

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Bendable Solar Cells from Stable, Flexible, and Transparent Conducting Electrodes Fabricated Using a Nitrogen-Doped Ultrathin Copper Film. / Zhao, Guoqing; Kim, Soo Min; Lee, Sang Geul; Bae, Tae Sung; Mun, Chae Won; Lee, Sunghun; Yu, Huashun; Lee, Gun Hwan; Lee, Haeseok; Song, Myungkwan; Yun, Jungheum.

In: Advanced Functional Materials, Vol. 26, No. 23, 20.06.2016, p. 4180-4191.

Research output: Contribution to journalArticle

Zhao, Guoqing ; Kim, Soo Min ; Lee, Sang Geul ; Bae, Tae Sung ; Mun, Chae Won ; Lee, Sunghun ; Yu, Huashun ; Lee, Gun Hwan ; Lee, Haeseok ; Song, Myungkwan ; Yun, Jungheum. / Bendable Solar Cells from Stable, Flexible, and Transparent Conducting Electrodes Fabricated Using a Nitrogen-Doped Ultrathin Copper Film. In: Advanced Functional Materials. 2016 ; Vol. 26, No. 23. pp. 4180-4191.
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