Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications

Tukaram D. Dongale; Sagar S. Khot; Akshay A. Patil; Siddhesh V. Wagh; Prashant B. Patil; Deepak P. Dubal; Tae Geun Kim

doi:10.1016/j.matdes.2021.109493

Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications

Tukaram D. Dongale, Sagar S. Khot, Akshay A. Patil, Siddhesh V. Wagh, Prashant B. Patil, Deepak P. Dubal, Tae Geun Kim

School of Electrical Engineering

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (10³) and retention (10⁴ s) non-volatile memory properties with a good memory window (10³) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na₂SO_4, Li₂SO₄, and Na₂SO₄: Li₂SO₄). It was revealed that the NFO thin film shows improved electrochemical performance in Na₂SO₄ electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm² current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na₂SO₄ electrolyte than other electrolytes. The diffusion coefficient of different ions (D_Na+, D_Li+ and D_Na+:Li+) were found to be 9.975 × 10⁻¹⁰ cm² s⁻¹, 3.292 × 10⁻¹¹ cm² s⁻¹, 2 × 10⁻¹⁰ cm² s⁻¹, respectively. A high diffusion coefficient was found for Na⁺ ions, indicating rapid Na⁺ transport with NFO thin-film electrodes

Original language	English
Article number	109493
Journal	Materials and Design
Volume	201
DOIs	https://doi.org/10.1016/j.matdes.2021.109493
Publication status	Published - 2021 Mar

Keywords

Aqueous battery
Data storage materials
Energy storage materials
Memristive device
Nickel ferrite
Resistive switching

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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10.1016/j.matdes.2021.109493

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@article{0d46de8c37b1413ca6877654f8c04f8a,

title = "Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications",

abstract = "Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (103) and retention (104 s) non-volatile memory properties with a good memory window (103) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na2SO4, Li2SO4, and Na2SO4: Li2SO4). It was revealed that the NFO thin film shows improved electrochemical performance in Na2SO4 electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm2 current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na2SO4 electrolyte than other electrolytes. The diffusion coefficient of different ions (DNa+, DLi+ and DNa+:Li+) were found to be 9.975 × 10−10 cm2 s−1, 3.292 × 10−11 cm2 s−1, 2 × 10−10 cm2 s−1, respectively. A high diffusion coefficient was found for Na+ ions, indicating rapid Na+ transport with NFO thin-film electrodes",

keywords = "Aqueous battery, Data storage materials, Energy storage materials, Memristive device, Nickel ferrite, Resistive switching",

author = "Dongale, {Tukaram D.} and Khot, {Sagar S.} and Patil, {Akshay A.} and Wagh, {Siddhesh V.} and Patil, {Prashant B.} and Dubal, {Deepak P.} and Kim, {Tae Geun}",

note = "Funding Information: This study was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government under Grant No. 2016R1A3B1908249 . Publisher Copyright: {\textcopyright} 2021 The Authors",

year = "2021",

month = mar,

doi = "10.1016/j.matdes.2021.109493",

language = "English",

volume = "201",

journal = "Materials and Design",

issn = "0261-3069",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Bifunctional nanoparticulated nickel ferrite thin films

T2 - Resistive memory and aqueous battery applications

AU - Dongale, Tukaram D.

AU - Khot, Sagar S.

AU - Patil, Akshay A.

AU - Wagh, Siddhesh V.

AU - Patil, Prashant B.

AU - Dubal, Deepak P.

AU - Kim, Tae Geun

N1 - Funding Information: This study was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government under Grant No. 2016R1A3B1908249 . Publisher Copyright: © 2021 The Authors

PY - 2021/3

Y1 - 2021/3

N2 - Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (103) and retention (104 s) non-volatile memory properties with a good memory window (103) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na2SO4, Li2SO4, and Na2SO4: Li2SO4). It was revealed that the NFO thin film shows improved electrochemical performance in Na2SO4 electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm2 current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na2SO4 electrolyte than other electrolytes. The diffusion coefficient of different ions (DNa+, DLi+ and DNa+:Li+) were found to be 9.975 × 10−10 cm2 s−1, 3.292 × 10−11 cm2 s−1, 2 × 10−10 cm2 s−1, respectively. A high diffusion coefficient was found for Na+ ions, indicating rapid Na+ transport with NFO thin-film electrodes

AB - Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (103) and retention (104 s) non-volatile memory properties with a good memory window (103) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na2SO4, Li2SO4, and Na2SO4: Li2SO4). It was revealed that the NFO thin film shows improved electrochemical performance in Na2SO4 electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm2 current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na2SO4 electrolyte than other electrolytes. The diffusion coefficient of different ions (DNa+, DLi+ and DNa+:Li+) were found to be 9.975 × 10−10 cm2 s−1, 3.292 × 10−11 cm2 s−1, 2 × 10−10 cm2 s−1, respectively. A high diffusion coefficient was found for Na+ ions, indicating rapid Na+ transport with NFO thin-film electrodes

KW - Aqueous battery

KW - Data storage materials

KW - Energy storage materials

KW - Memristive device

KW - Nickel ferrite

KW - Resistive switching

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U2 - 10.1016/j.matdes.2021.109493

DO - 10.1016/j.matdes.2021.109493

M3 - Article

AN - SCOPUS:85099798301

SN - 0261-3069

VL - 201

JO - Materials and Design

JF - Materials and Design

M1 - 109493

ER -

Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications

Abstract

Keywords

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