BODIPY appended cone-calix[4]arene: selective fluorescence changes upon Ca2+ binding

Hyun Jung Kim, Jong Seung Kim

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

BODIPY appended new calix[4]arene diethyl ester (1) has been synthesized in the cone conformation. With respect to fluorescence intensity changes upon metal ion complexation, 1 shows a Ca2+ ion selectivity over other metal cations. Presence of two proximal hydroxyl groups and two facing ethyl esters in BODIPY-calix[4]arene were observed to play an important role in exhibiting its selective Ca2+ ion binding.

Original languageEnglish
Pages (from-to)7051-7055
Number of pages5
JournalTetrahedron Letters
Volume47
Issue number39
DOIs
Publication statusPublished - 2006 Sep 25
Externally publishedYes

Fingerprint

Cones
Esters
Fluorescence
Ions
Complexation
Metals
Hydroxyl Radical
Metal ions
Conformations
Cations
4,4-difluoro-4-bora-3a,4a-diaza-s-indacene
calix(4)arene

Keywords

  • Calixarenes
  • Fluorescence
  • Reverse PET

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

BODIPY appended cone-calix[4]arene : selective fluorescence changes upon Ca2+ binding. / Kim, Hyun Jung; Kim, Jong Seung.

In: Tetrahedron Letters, Vol. 47, No. 39, 25.09.2006, p. 7051-7055.

Research output: Contribution to journalArticle

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