Boosting the electrocatalytic activities of SnO 2 electrodes for remediation of aqueous pollutants by doping with various metals

So Young Yang, Yeon Sik Choo, Soonhyun Kim, Sang Kyoo Lim, Jaesang Lee, Hyunwoong Park

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

The purpose of this study is to search for effective dopants and their optimal combinations to improve the electrocatalytic activity of the SnO 2 electrode for the remediation of aqueous pollutants. For this purpose, Sb was selected as the primary dopant for SnO 2 and six elements (Fe(III), Ni(II), Co(II), Ru(III), Ce(III), and Pd(II)) were also introduced into the optimized Sb-SnO 2 electrodes. The electrodes were checked for their electrochemical properties at different doping levels and tested for their electrocatalytic activities for the degradation of phenol and Eosin Y. In addition, RNO (N,N-dimethyl-p-nitrosoaniline) was used as a probe molecule for OH radicals to examine the reaction mechanism occurring at the electrodes. Sb with a 5-10at.% was most effective in making SnO 2 an electrocatalyst and Ni (∼1%) enhanced the degradation rate and TOC removal rate of phenol at the Sb-SnO 2 anode by a factor of 14 and 8, respectively. Fe also increased the activity moderately. Enhanced Ni-Sb-SnO 2 activity was also found for Eosin Y. The other co-dopants exhibited various degrees of positive or negative effects depending on the substrate. The lack of a correlation in the kinetics between substrate degradation and the RNO changes indicated that the primary electrocatalytic reactions may proceed via direct electron transfer and/or organic peroxy radical-mediation, not OH radical-mediation. Detailed analyses of the electrode surfaces (SEM, TEM, XRD, and XPS) and quantification of intermediates were carried out to obtain insight into the heterogeneous electrocatalytic reaction.

Original languageEnglish
Pages (from-to)317-325
Number of pages9
JournalApplied Catalysis B: Environmental
Volume111-112
DOIs
Publication statusPublished - 2012 Jan 12
Externally publishedYes

Fingerprint

Remediation
electrode
remediation
Metals
Doping (additives)
Electrodes
pollutant
metal
Eosine Yellowish-(YS)
Phenol
Degradation
degradation
Phenols
phenol
peroxy radical
substrate
Electrocatalysts
Substrates
Electrochemical properties
Chemical elements

Keywords

  • Antimony
  • Doping
  • Electrocatalytic
  • Sb-SnO
  • Water treatment

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Environmental Science(all)

Cite this

Boosting the electrocatalytic activities of SnO 2 electrodes for remediation of aqueous pollutants by doping with various metals. / Yang, So Young; Choo, Yeon Sik; Kim, Soonhyun; Lim, Sang Kyoo; Lee, Jaesang; Park, Hyunwoong.

In: Applied Catalysis B: Environmental, Vol. 111-112, 12.01.2012, p. 317-325.

Research output: Contribution to journalArticle

Yang, So Young ; Choo, Yeon Sik ; Kim, Soonhyun ; Lim, Sang Kyoo ; Lee, Jaesang ; Park, Hyunwoong. / Boosting the electrocatalytic activities of SnO 2 electrodes for remediation of aqueous pollutants by doping with various metals. In: Applied Catalysis B: Environmental. 2012 ; Vol. 111-112. pp. 317-325.
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