Bright, stable, and water-soluble CuInS2/ZnS nanocrystals passivated by cetyltrimethylammonium bromide

Jun Lee, Chang-Soo Han

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

We report a highly bright and stable aqueous dispersion of CuInS2/ZnS (CIS/ZnS) nanocrystals (NCs) using surfactant-assisted microemulsion and cold treatment. CIS/ZnS NCs were facilely synthesized via a stepwise, consecutive hybrid flow reactor approach. To stabilize the optical properties of hydrophobic CIS/ZnS NCs, cetyltrimethylammonium bromide (CTAB) was chosen as a matrix for aqueous phase transfer. As the result, a high quantum yield (QY) of 56.0% and excellent photostability were acquired in aqueous media. For removing excessive surfactants, cold treatment (4°C) of the CTAB-water solution was adopted to prevent further agglomeration of CIS/ZnS NCs, which could secure high stability over 6 months (less 2% reduction in QY). The optical features and structure of the obtained CTAB stabilized CIS/ZnS (CTAB-CIS/ZnS) NCs have been characterized by UV–vis and photoluminescence (PL) spectroscopies, XRD, XPS, EDX, and TEM. The high stability and PL of water soluble CTAB-CIS/ZnS NCs suggest their potential in nanoelectronics and bioapplications.

Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalNanoscale Research Letters
Volume10
Issue number1
DOIs
Publication statusPublished - 2015 Dec 1

Fingerprint

Nanocrystals
bromides
nanocrystals
Water
water
Quantum yield
Surface-Active Agents
Surface active agents
surfactants
photoluminescence
Nanoelectronics
Photoluminescence spectroscopy
Microemulsions
agglomeration
cetrimonium
Energy dispersive spectroscopy
Photoluminescence
Agglomeration
X ray photoelectron spectroscopy
Optical properties

Keywords

  • Cold treatment
  • CTAB
  • CuInS/ZnS nanocrystals
  • Photostability

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Bright, stable, and water-soluble CuInS2/ZnS nanocrystals passivated by cetyltrimethylammonium bromide. / Lee, Jun; Han, Chang-Soo.

In: Nanoscale Research Letters, Vol. 10, No. 1, 01.12.2015, p. 1-9.

Research output: Contribution to journalArticle

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