Calcium sulfate hemihydrate powders with a controlled morphology for use as bone cement

Peng Wang, Eun Jung Lee, Chee Sung Park, Byung Ho Yoon, Du Sik Shin, Hyoun Ee Kim, Young Hag Koh, Soon Hyo Park

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

Calcium sulfate hemihydrate (CSH) powders were synthesized for use as bone cement by heat treating calcium sulfate dihydrate (CSD) powders in boiling CaCl2 solutions with various CaCl2 concentrations, ranging from 23.5 to 35.5 wt%, in order to control their morphology. All of the prepared CSH powders showed X-ray diffraction peaks corresponding to the CSH structure without any secondary phases, implying complete conversion from the CSD phase to the CSH phase. It was also observed that the concentration of CaCl2 significantly affected the morphology of the CSH powder that was synthesized. In other words, as the CaCl2 concentration was decreased from 35.5 to 23.5 wt%, the morphology notably changed from long-and-slim hexagonal rods with an aspect ratio of 5.5 to fat-and-short hexagonal columns with an aspect ratio of 1.4. This reduction in the aspect ratio led to a significant improvement in the compressive strength of the CSD cement prepared by mixing the CSH powders with water.

Original languageEnglish
Pages (from-to)2039-2042
Number of pages4
JournalJournal of the American Ceramic Society
Volume91
Issue number6
DOIs
Publication statusPublished - 2008 Jun

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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