Calculation of phase equilibrium for water+carbon dioxide system using nonrandom lattice fluid equation of state

Cheong Hoon Kwon, Chang H. Lee, Jeong Won Kang

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

For the geological sequestration of carbon dioxide to prevent global warming, the phase equilibrium data for water and carbon dioxide mixture play an important role in process design and operation. In this work, the nonrandom lattice fluid equation of state with hydrogen bonding (NLF-HB EOS) was applied for the prediction of phase equilibrium of mixtures containing water and carbon dioxide. A new set of pure component parameters for carbon dioxide above critical condition was found and optimum binary interaction parameters were reported to correlate mutual solubility of mixtures. The calculated results were compared with the Peng-Robinson Equation of State with the conventional mixing rule (PR-EOS) and the Wong-Sandler mixing rule (PR-WS-EOS). The calculation results show that NLF-HB EOS can correlate mutual solubility of water+carbon dioxide mixtures with reasonable accuracy within a single theoretical framework.

Original languageEnglish
Pages (from-to)278-283
Number of pages6
JournalKorean Journal of Chemical Engineering
Volume27
Issue number1
DOIs
Publication statusPublished - 2010 Jan 1

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Equations of state
Carbon Dioxide
Phase equilibria
Carbon dioxide
Fluids
Water
Solubility
Global warming
Process design
Hydrogen bonds

Keywords

  • Carbon Dioxide
  • Equation of State
  • Mutual Solubility
  • Water

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Calculation of phase equilibrium for water+carbon dioxide system using nonrandom lattice fluid equation of state. / Kwon, Cheong Hoon; Lee, Chang H.; Kang, Jeong Won.

In: Korean Journal of Chemical Engineering, Vol. 27, No. 1, 01.01.2010, p. 278-283.

Research output: Contribution to journalArticle

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