Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

Jihee Cho; Jinwoo Shin; Minjung Kang; Peter Verwilst; Changhyun Lim; Hanbin Yoo; Jeung Gon Kim; Xingcai Zhang; Chang Seop Hong; Jong Seung Kim; Sanghee Kim

doi:10.1039/d1cc04950j

Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

Jihee Cho, Jinwoo Shin, Minjung Kang, Peter Verwilst, Changhyun Lim, Hanbin Yoo, Jeung Gon Kim, Xingcai Zhang, Chang Seop Hong, Jong Seung Kim, Sanghee Kim

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on"fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.

Original language	English
Pages (from-to)	12139-12142
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	91
DOIs	https://doi.org/10.1039/d1cc04950j
Publication status	Published - 2021 Nov 25

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d1cc04950j

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title = "Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection",

abstract = "A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces {"}turn-on{"}fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.",

author = "Jihee Cho and Jinwoo Shin and Minjung Kang and Peter Verwilst and Changhyun Lim and Hanbin Yoo and Kim, {Jeung Gon} and Xingcai Zhang and Hong, {Chang Seop} and Kim, {Jong Seung} and Sanghee Kim",

note = "Funding Information: This work was supported by no. 2018R1A5A2024425 (S. K.) and CRI project no. 2018R1A3B1052702 (J. S. K.) of National Research Foundation (NRF) grant funded by Korea government (MSIT). This research was also supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (no. 2020R1I1A1A01073399, J. C.), and PAL (C. S. H.). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

month = nov,

day = "25",

doi = "10.1039/d1cc04950j",

language = "English",

volume = "57",

pages = "12139--12142",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "91",

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TY - JOUR

T1 - Calix[

T2 - N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

AU - Cho, Jihee

AU - Shin, Jinwoo

AU - Kang, Minjung

AU - Verwilst, Peter

AU - Lim, Changhyun

AU - Yoo, Hanbin

AU - Kim, Jeung Gon

AU - Zhang, Xingcai

AU - Hong, Chang Seop

AU - Kim, Jong Seung

AU - Kim, Sanghee

N1 - Funding Information: This work was supported by no. 2018R1A5A2024425 (S. K.) and CRI project no. 2018R1A3B1052702 (J. S. K.) of National Research Foundation (NRF) grant funded by Korea government (MSIT). This research was also supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (no. 2020R1I1A1A01073399, J. C.), and PAL (C. S. H.). Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/11/25

Y1 - 2021/11/25

N2 - A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on"fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.

AB - A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces "turn-on"fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.

UR - http://www.scopus.com/inward/record.url?scp=85119839166&partnerID=8YFLogxK

U2 - 10.1039/d1cc04950j

DO - 10.1039/d1cc04950j

M3 - Article

C2 - 34724524

AN - SCOPUS:85119839166

SN - 1359-7345

VL - 57

SP - 12139

EP - 12142

JO - Chemical Communications

JF - Chemical Communications

IS - 91

ER -

Calix[: N] triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

Abstract

ASJC Scopus subject areas

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