Carbon-encapsulated NiFe nanoparticles as a bifunctional electrocatalyst for high-efficiency overall water splitting

Sung Woo Park, Inha Kim, Seung Ik Oh, Jae Chan Kim, Dong-Wan Kim

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The use of non-noble metal-based electrocatalysts to achieve highly efficient and cost-effective water splitting has encountered major challenges, particularly with respect to catalytic activity, stability, cost, and ease of manufacture. Herein, few carbon-layers-encapsulated NiFe nanoparticles (NiFe@C) were prepared as a simple and effective facile top-down approach when used with the electrical explosion of wire process as a bifunctional electrocatalyst to achieve higher overall water splitting efficiency. Uniformly surrounding the unique structure of NiFe nanoparticles (∼15 nm in diameter) by a small number of carbon layers can be accomplished via one-pot synthesis by exploding NiFe wires in an ethanol media. The simply prepared NiFe@C catalyst exhibits remarkable catalytic activity and stability in alkaline solution for both OER (oxygen evolution reaction) and HER (hydrogen evolution reaction). When bifunctional electrocatalysts are utilized as electrodes for both cathode and anode reactions in a single electrolyzer, outstanding catalytic performance was achieved with an operational voltage of 1.575 V at a current density of 10 mA cm−2. Most importantly, the electrodes displayed superior catalytic stability in the overall water splitting reaction for 200 h. Consequently, this work proposes and evaluates this effective new strategy for the synthesis of low-cost, highly efficient and stable bifunctional electrocatalysts.

Original languageEnglish
Pages (from-to)266-274
Number of pages9
JournalJournal of Catalysis
Volume366
DOIs
Publication statusPublished - 2018 Oct 1

Fingerprint

water splitting
electrocatalysts
Electrocatalysts
Carbon
Nanoparticles
nanoparticles
Water
carbon
catalytic activity
Catalyst activity
Exploding wires
exploding wires
costs
Costs
Electrodes
electrodes
synthesis
Explosions
explosions
Hydrogen

Keywords

  • Bifunctional electrocatalysts
  • Carbon-encapsulating
  • Electrical explosion of wire
  • NiFe nanoparticles
  • Water splitting

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Carbon-encapsulated NiFe nanoparticles as a bifunctional electrocatalyst for high-efficiency overall water splitting. / Park, Sung Woo; Kim, Inha; Oh, Seung Ik; Kim, Jae Chan; Kim, Dong-Wan.

In: Journal of Catalysis, Vol. 366, 01.10.2018, p. 266-274.

Research output: Contribution to journalArticle

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