Carbon microspheres with well-developed micro- and mesopores as excellent selenium host materials for lithium-selenium batteries with superior performances

Gi Dae Park, Jong Hwa Kim, Jung Kul Lee, Yun Chan Kang

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

As host materials for efficient selenium storage and utilization, porous carbon materials with optimized and suitable pore structures are important in the development of high-performance Li-Se batteries. Herein, the synergetic effect of micro- and mesopores of carbon materials on the conversion reaction of loaded chain-structured Sen is studied for superior Li-Se batteries. Carbon microspheres with well-developed micro- and mesopores are synthesized by spray pyrolysis. Carbon-vanadium oxide composite microspheres synthesized by spray pyrolysis transform into microporous carbon microspheres (P-carbon) by etching of vanadium oxide. An additional post-treatment of the spray-pyrolysis product at 400 °C yields carbon microspheres (A4-carbon) with well-developed micro- and mesopores by etching of vanadium oxide. The presence of both micro- and mesopores in carbon is desirable to achieve a fast conversion reaction of Sen in the Se-loaded carbon microspheres. The Se-loaded carbon microspheres with well-developed micro- and mesopores (A4-carbon/Se) exhibit higher capacities and stable long-term cycling performances compared with similar microspheres with only micropores (P-carbon/Se). The discharge capacities of P-carbon/Se and A4-carbon/Se at the 500th cycle at a current density of 0.5 A g−1 are 403 and 582 mA h g−1, respectively. Moreover, A4-carbon/Se microspheres exhibit a stable reversible capacity of 343 mA h g−1 after 2000 cycles even at a high current density of 2.0 A g−1; their capacity retention calculated from the 3rd cycle is 87%.

Original languageEnglish
Pages (from-to)21410-21418
Number of pages9
JournalJournal of Materials Chemistry A
Volume6
Issue number43
DOIs
Publication statusPublished - 2018 Jan 1

Fingerprint

Selenium
Microspheres
Lithium
Carbon
Vanadium
Spray pyrolysis
Oxides
Etching
Current density
Pore structure

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Carbon microspheres with well-developed micro- and mesopores as excellent selenium host materials for lithium-selenium batteries with superior performances. / Park, Gi Dae; Kim, Jong Hwa; Lee, Jung Kul; Kang, Yun Chan.

In: Journal of Materials Chemistry A, Vol. 6, No. 43, 01.01.2018, p. 21410-21418.

Research output: Contribution to journalArticle

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