Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

Chang Hun Lee; Yin Hua Jin; Joongyeon Kim; Sun Hee Park; Byung Hee Chun; Sung Hyun Kim

doi:10.1016/j.jiec.2013.01.007

Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

Chang Hun Lee, Yin Hua Jin, Joongyeon Kim, Sun Hee Park, Byung Hee Chun, Sung Hyun Kim

Honorary professors

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co₃O₄/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co₃O₄ relative to ZSM-5 were tested.

Original language	English
Pages (from-to)	1443-1447
Number of pages	5
Journal	Journal of Industrial and Engineering Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1016/j.jiec.2013.01.007
Publication status	Published - 2013 Sep 25

Keywords

C5 compounds
Cobalt oxide
Dechlorination
Ion exchange
Metal oxide/ZSM-5

ASJC Scopus subject areas

Chemical Engineering(all)

Access to Document

10.1016/j.jiec.2013.01.007

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Cite this

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title = "Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts",

abstract = "In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co3O4/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co3O4 relative to ZSM-5 were tested.",

keywords = "C5 compounds, Cobalt oxide, Dechlorination, Ion exchange, Metal oxide/ZSM-5",

author = "Lee, {Chang Hun} and Jin, {Yin Hua} and Joongyeon Kim and Park, {Sun Hee} and Chun, {Byung Hee} and Kim, {Sung Hyun}",

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T1 - Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

AU - Lee, Chang Hun

AU - Jin, Yin Hua

AU - Kim, Joongyeon

AU - Park, Sun Hee

AU - Chun, Byung Hee

AU - Kim, Sung Hyun

PY - 2013/9/25

Y1 - 2013/9/25

N2 - In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co3O4/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co3O4 relative to ZSM-5 were tested.

AB - In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co3O4/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co3O4 relative to ZSM-5 were tested.

KW - C5 compounds

KW - Cobalt oxide

KW - Dechlorination

KW - Ion exchange

KW - Metal oxide/ZSM-5

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