Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

Chang Hun Lee; Yin Hua Jin; Joongyeon Kim; Sun Hee Park; Byung Hee Chun; Sung Hyun Kim

doi:10.1016/j.jiec.2013.01.007

Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

Chang Hun Lee, Yin Hua Jin, Joongyeon Kim, Sun Hee Park, Byung Hee Chun, Sung Hyun Kim

* Honorary professors

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co₃O₄/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co₃O₄ relative to ZSM-5 were tested.

Original language	English
Pages (from-to)	1443-1447
Number of pages	5
Journal	Journal of Industrial and Engineering Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1016/j.jiec.2013.01.007
Publication status	Published - 2013 Sep 25

Keywords

C5 compounds
Cobalt oxide
Dechlorination
Ion exchange
Metal oxide/ZSM-5

ASJC Scopus subject areas

Chemical Engineering(all)

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10.1016/j.jiec.2013.01.007

Cite this

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title = "Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts",

abstract = "In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co3O4/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co3O4 relative to ZSM-5 were tested.",

keywords = "C5 compounds, Cobalt oxide, Dechlorination, Ion exchange, Metal oxide/ZSM-5",

author = "Lee, {Chang Hun} and Jin, {Yin Hua} and Joongyeon Kim and Park, {Sun Hee} and Chun, {Byung Hee} and Kim, {Sung Hyun}",

note = "Funding Information: This work was supported by the Human Resources Development the Korea Institute of Energy Technology Evaluation and Planning (20114010203050) grant funded by the Korean government Ministry of Knowledge Economy .",

year = "2013",

month = sep,

day = "25",

doi = "10.1016/j.jiec.2013.01.007",

language = "English",

volume = "19",

pages = "1443--1447",

journal = "Journal of Industrial and Engineering Chemistry",

issn = "1226-086X",

publisher = "Korean Society of Industrial Engineering Chemistry",

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TY - JOUR

T1 - Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

AU - Lee, Chang Hun

AU - Jin, Yin Hua

AU - Kim, Joongyeon

AU - Park, Sun Hee

AU - Chun, Byung Hee

AU - Kim, Sung Hyun

N1 - Funding Information: This work was supported by the Human Resources Development the Korea Institute of Energy Technology Evaluation and Planning (20114010203050) grant funded by the Korean government Ministry of Knowledge Economy .

PY - 2013/9/25

Y1 - 2013/9/25

N2 - In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co3O4/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co3O4 relative to ZSM-5 were tested.

AB - In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co3O4/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co3O4 relative to ZSM-5 were tested.

KW - C5 compounds

KW - Cobalt oxide

KW - Dechlorination

KW - Ion exchange

KW - Metal oxide/ZSM-5

UR - http://www.scopus.com/inward/record.url?scp=84880589250&partnerID=8YFLogxK

U2 - 10.1016/j.jiec.2013.01.007

DO - 10.1016/j.jiec.2013.01.007

M3 - Article

AN - SCOPUS:84880589250

VL - 19

SP - 1443

EP - 1447

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

SN - 1226-086X

IS - 5

ER -

Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

Abstract

Keywords

ASJC Scopus subject areas

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