Abstract
Combinative dechloro/dehydro catenation of 1,1-dichlorotetraphenylsilole 1 with < 150 mol% of various inorganic hydrides in THF at 25°C produces optoelectronic polysiloles 2 in high yield. Similarly, cocatenation of 1 and 1,1-dichlorotetraphenylgermole 4 (9:1 mole ratio) using 110 mol% of Red-Al in THF at 25°C gives poly(silole-co-germole) 5 in high yield. The polymers emit green light at 520nm and are strongly electroluminescent at 520nm.
| Original language | English |
|---|---|
| Pages (from-to) | 243-248 |
| Number of pages | 6 |
| Journal | Molecular Crystals and Liquid Crystals |
| Volume | 425 |
| DOIs | |
| Publication status | Published - 2004 |
| Externally published | Yes |
Keywords
- Catenation
- Electroluminescence
- Green light
- Inorganic hydride
- Photoluminescence
- Polysilole
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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Cite this
Kim, B. II., Cho, M. S., Kong, J. I., Woo, H. G., Lee, S. W., & Lee, C. J. (2004). Catenation of 1,1-dichlorotertaphenylsilole and 1,1- dichlorotetraphenylgermole to optoelectronic polymers. Molecular Crystals and Liquid Crystals, 425, 243-248. https://doi.org/10.1080/15421400490506883