Catenation of 1,1-dichlorotertaphenylsilole and 1,1- dichlorotetraphenylgermole to optoelectronic polymers

Bo IIye Kim; Myong Shik Cho; Jung Il Kong; Hee Gweon Woo; Seung Won Lee; Cheol Jin Lee

doi:10.1080/15421400490506883

Catenation of 1,1-dichlorotertaphenylsilole and 1,1- dichlorotetraphenylgermole to optoelectronic polymers

Bo IIye Kim, Myong Shik Cho, Jung Il Kong, Hee Gweon Woo, Seung Won Lee, Cheol Jin Lee

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Combinative dechloro/dehydro catenation of 1,1-dichlorotetraphenylsilole 1 with < 150 mol% of various inorganic hydrides in THF at 25°C produces optoelectronic polysiloles 2 in high yield. Similarly, cocatenation of 1 and 1,1-dichlorotetraphenylgermole 4 (9:1 mole ratio) using 110 mol% of Red-Al in THF at 25°C gives poly(silole-co-germole) 5 in high yield. The polymers emit green light at 520nm and are strongly electroluminescent at 520nm.

Original language	English
Pages (from-to)	243-248
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals
Volume	425
DOIs	https://doi.org/10.1080/15421400490506883
Publication status	Published - 2004
Externally published	Yes

Keywords

Catenation
Electroluminescence
Green light
Inorganic hydride
Photoluminescence
Polysilole

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Catenation of 1,1-dichlorotertaphenylsilole and 1,1- dichlorotetraphenylgermole to optoelectronic polymers",

abstract = "Combinative dechloro/dehydro catenation of 1,1-dichlorotetraphenylsilole 1 with < 150 mol% of various inorganic hydrides in THF at 25°C produces optoelectronic polysiloles 2 in high yield. Similarly, cocatenation of 1 and 1,1-dichlorotetraphenylgermole 4 (9:1 mole ratio) using 110 mol% of Red-Al in THF at 25°C gives poly(silole-co-germole) 5 in high yield. The polymers emit green light at 520nm and are strongly electroluminescent at 520nm.",

keywords = "Catenation, Electroluminescence, Green light, Inorganic hydride, Photoluminescence, Polysilole",

author = "Kim, {Bo IIye} and Cho, {Myong Shik} and Kong, {Jung Il} and Woo, {Hee Gweon} and Lee, {Seung Won} and Lee, {Cheol Jin}",

note = "Funding Information: This research was supported by the Korea Science and Engineering Foundation (Project No. R01-2001-000-00053-0; 2003). S. W. L. is grateful to the Korea Science and Engineering Foundation (Project No. R01-2002-000-00119-0; 2003) for support of his research reported herein. The authors greatly acknowledge the kind advice and helpful discussions provided by Professor Kunio Oka in Osaka Prefecture University and Prof. Honglae Sohn at Chosun University. Copyright: Copyright 2009 Elsevier B.V., All rights reserved.",

year = "2004",

doi = "10.1080/15421400490506883",

language = "English",

volume = "425",

pages = "243--248",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Catenation of 1,1-dichlorotertaphenylsilole and 1,1- dichlorotetraphenylgermole to optoelectronic polymers

AU - Kim, Bo IIye

AU - Cho, Myong Shik

AU - Kong, Jung Il

AU - Woo, Hee Gweon

AU - Lee, Seung Won

AU - Lee, Cheol Jin

N1 - Funding Information: This research was supported by the Korea Science and Engineering Foundation (Project No. R01-2001-000-00053-0; 2003). S. W. L. is grateful to the Korea Science and Engineering Foundation (Project No. R01-2002-000-00119-0; 2003) for support of his research reported herein. The authors greatly acknowledge the kind advice and helpful discussions provided by Professor Kunio Oka in Osaka Prefecture University and Prof. Honglae Sohn at Chosun University. Copyright: Copyright 2009 Elsevier B.V., All rights reserved.

PY - 2004

Y1 - 2004

N2 - Combinative dechloro/dehydro catenation of 1,1-dichlorotetraphenylsilole 1 with < 150 mol% of various inorganic hydrides in THF at 25°C produces optoelectronic polysiloles 2 in high yield. Similarly, cocatenation of 1 and 1,1-dichlorotetraphenylgermole 4 (9:1 mole ratio) using 110 mol% of Red-Al in THF at 25°C gives poly(silole-co-germole) 5 in high yield. The polymers emit green light at 520nm and are strongly electroluminescent at 520nm.

AB - Combinative dechloro/dehydro catenation of 1,1-dichlorotetraphenylsilole 1 with < 150 mol% of various inorganic hydrides in THF at 25°C produces optoelectronic polysiloles 2 in high yield. Similarly, cocatenation of 1 and 1,1-dichlorotetraphenylgermole 4 (9:1 mole ratio) using 110 mol% of Red-Al in THF at 25°C gives poly(silole-co-germole) 5 in high yield. The polymers emit green light at 520nm and are strongly electroluminescent at 520nm.

KW - Catenation

KW - Electroluminescence

KW - Green light

KW - Inorganic hydride

KW - Photoluminescence

KW - Polysilole

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U2 - 10.1080/15421400490506883

DO - 10.1080/15421400490506883

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VL - 425

SP - 243

EP - 248

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

SN - 1542-1406

ER -

Catenation of 1,1-dichlorotertaphenylsilole and 1,1- dichlorotetraphenylgermole to optoelectronic polymers

Abstract

Keywords

ASJC Scopus subject areas

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