Characteristics of ZnO-B2O3-SiO2-CaO glass frits prepared by spray pyrolysis as inorganic binder for Cu electrode

Young Jun Hong; Dae Soo Jung; Hye Young Koo; Jung Hyun Kim; You Na Ko; Yun Chan Kang

doi:10.1016/j.jallcom.2011.05.038

Characteristics of ZnO-B₂O₃-SiO₂-CaO glass frits prepared by spray pyrolysis as inorganic binder for Cu electrode

Young Jun Hong, Dae Soo Jung, Hye Young Koo, Jung Hyun Kim, You Na Ko, Yun Chan Kang

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

ZnO-B₂O₃-SiO₂-CaO glass frits were directly prepared by high temperature spray pyrolysis for use in Cu electrodes. The frits prepared at temperatures above 1400 °C were spherical, amorphous, of fine size and dense structure. The mean particle size and geometric standard deviation of the frits prepared at 1400 °C were 0.87 μm and 1.37, respectively. The temperatures of glass transition, crystallization and melting were 454, 534 and 800 °C, respectively. The glass layer fired at 800 °C had a dense structure due to the material's complete melting, despite some crystals being observed by SEM. A copper electrode formed from copper paste with glass frits had a dense structure when fired at 800 °C. The specific resistances of electrodes formed from copper paste with and without glass frits were 2.5 and 8.5 μΩ cm, respectively.

Original language	English
Pages (from-to)	8077-8081
Number of pages	5
Journal	Journal of Alloys and Compounds
Volume	509
Issue number	31
DOIs	https://doi.org/10.1016/j.jallcom.2011.05.038
Publication status	Published - 2011 Aug 4
Externally published	Yes

Keywords

Chemical synthesis
Electrical conductivity
Glasses
Metals

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/j.jallcom.2011.05.038

Cite this

@article{d88a6c2713a24f888cda294cab334531,

title = "Characteristics of ZnO-B2O3-SiO2-CaO glass frits prepared by spray pyrolysis as inorganic binder for Cu electrode",

abstract = "ZnO-B2O3-SiO2-CaO glass frits were directly prepared by high temperature spray pyrolysis for use in Cu electrodes. The frits prepared at temperatures above 1400 °C were spherical, amorphous, of fine size and dense structure. The mean particle size and geometric standard deviation of the frits prepared at 1400 °C were 0.87 μm and 1.37, respectively. The temperatures of glass transition, crystallization and melting were 454, 534 and 800 °C, respectively. The glass layer fired at 800 °C had a dense structure due to the material's complete melting, despite some crystals being observed by SEM. A copper electrode formed from copper paste with glass frits had a dense structure when fired at 800 °C. The specific resistances of electrodes formed from copper paste with and without glass frits were 2.5 and 8.5 μΩ cm, respectively.",

keywords = "Chemical synthesis, Electrical conductivity, Glasses, Metals",

author = "Hong, {Young Jun} and Jung, {Dae Soo} and Koo, {Hye Young} and Kim, {Jung Hyun} and Ko, {You Na} and Kang, {Yun Chan}",

note = "Funding Information: This study was supported by a grant (M2009010025) from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy (MKE), Republic of Korea. This study was supported by Seoul R & BD Program (WR090671). This study was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MEST) (No. 2009-0074023).",

year = "2011",

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doi = "10.1016/j.jallcom.2011.05.038",

language = "English",

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T1 - Characteristics of ZnO-B2O3-SiO2-CaO glass frits prepared by spray pyrolysis as inorganic binder for Cu electrode

AU - Hong, Young Jun

AU - Jung, Dae Soo

AU - Koo, Hye Young

AU - Kim, Jung Hyun

AU - Ko, You Na

AU - Kang, Yun Chan

N1 - Funding Information: This study was supported by a grant (M2009010025) from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy (MKE), Republic of Korea. This study was supported by Seoul R & BD Program (WR090671). This study was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MEST) (No. 2009-0074023).

PY - 2011/8/4

Y1 - 2011/8/4

N2 - ZnO-B2O3-SiO2-CaO glass frits were directly prepared by high temperature spray pyrolysis for use in Cu electrodes. The frits prepared at temperatures above 1400 °C were spherical, amorphous, of fine size and dense structure. The mean particle size and geometric standard deviation of the frits prepared at 1400 °C were 0.87 μm and 1.37, respectively. The temperatures of glass transition, crystallization and melting were 454, 534 and 800 °C, respectively. The glass layer fired at 800 °C had a dense structure due to the material's complete melting, despite some crystals being observed by SEM. A copper electrode formed from copper paste with glass frits had a dense structure when fired at 800 °C. The specific resistances of electrodes formed from copper paste with and without glass frits were 2.5 and 8.5 μΩ cm, respectively.

AB - ZnO-B2O3-SiO2-CaO glass frits were directly prepared by high temperature spray pyrolysis for use in Cu electrodes. The frits prepared at temperatures above 1400 °C were spherical, amorphous, of fine size and dense structure. The mean particle size and geometric standard deviation of the frits prepared at 1400 °C were 0.87 μm and 1.37, respectively. The temperatures of glass transition, crystallization and melting were 454, 534 and 800 °C, respectively. The glass layer fired at 800 °C had a dense structure due to the material's complete melting, despite some crystals being observed by SEM. A copper electrode formed from copper paste with glass frits had a dense structure when fired at 800 °C. The specific resistances of electrodes formed from copper paste with and without glass frits were 2.5 and 8.5 μΩ cm, respectively.

KW - Chemical synthesis

KW - Electrical conductivity

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KW - Metals

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