Characterization of Si3N4/SiC nanocomposite by Raman scattering and XPS

Woo Seok Cho; Yoon Suk Oh; Chang Sam Kim; Minoru Osada; Masato Kakihana; Dae Soon Lim; Deock Soo Cheong

doi:10.1016/S0925-8388(99)00007-9

Characterization of Si₃N₄/SiC nanocomposite by Raman scattering and XPS

Woo Seok Cho, Yoon Suk Oh, Chang Sam Kim, Minoru Osada, Masato Kakihana, Dae Soon Lim, Deock Soo Cheong

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

We have synthesized Si₃N₄/SiC nanocomposites using a commercial polymer. The formed Si₃N₄/SiC nanocomposites have been studied using Raman scattering and X-ray photoelectron spectroscopy (XPS). The Raman scattering measurements showed that the formation of SiC started at 1200°C and that the main phase was 3C-SiC. The XPS results suggested that the SiC nanoparticles were formed by a chemical reaction of Si provided from Si₃N₄ with free carbon obtained by pyrolysis of polymer. The XPS results also indicated that residual carbon reacted with N₂ to form CN_x, which remained as an impurity phase in the final product.

Original language	English
Pages (from-to)	255-259
Number of pages	5
Journal	Journal of Alloys and Compounds
Volume	285
Issue number	1-2 Complete
DOIs	https://doi.org/10.1016/S0925-8388(99)00007-9
Publication status	Published - 1999
Externally published	Yes

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0925-8388(99)00007-9

Cite this

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title = "Characterization of Si3N4/SiC nanocomposite by Raman scattering and XPS",

abstract = "We have synthesized Si3N4/SiC nanocomposites using a commercial polymer. The formed Si3N4/SiC nanocomposites have been studied using Raman scattering and X-ray photoelectron spectroscopy (XPS). The Raman scattering measurements showed that the formation of SiC started at 1200°C and that the main phase was 3C-SiC. The XPS results suggested that the SiC nanoparticles were formed by a chemical reaction of Si provided from Si3N4 with free carbon obtained by pyrolysis of polymer. The XPS results also indicated that residual carbon reacted with N2 to form CNx, which remained as an impurity phase in the final product.",

author = "Cho, {Woo Seok} and Oh, {Yoon Suk} and Kim, {Chang Sam} and Minoru Osada and Masato Kakihana and Lim, {Dae Soon} and Cheong, {Deock Soo}",

note = "Funding Information: This work was supported by a KIST-2000 program from the Ministry of Science and Technology of Korea. ",

year = "1999",

doi = "10.1016/S0925-8388(99)00007-9",

language = "English",

volume = "285",

pages = "255--259",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier BV",

number = "1-2 Complete",

}

TY - JOUR

T1 - Characterization of Si3N4/SiC nanocomposite by Raman scattering and XPS

AU - Cho, Woo Seok

AU - Oh, Yoon Suk

AU - Kim, Chang Sam

AU - Osada, Minoru

AU - Kakihana, Masato

AU - Lim, Dae Soon

AU - Cheong, Deock Soo

N1 - Funding Information: This work was supported by a KIST-2000 program from the Ministry of Science and Technology of Korea.

PY - 1999

Y1 - 1999

N2 - We have synthesized Si3N4/SiC nanocomposites using a commercial polymer. The formed Si3N4/SiC nanocomposites have been studied using Raman scattering and X-ray photoelectron spectroscopy (XPS). The Raman scattering measurements showed that the formation of SiC started at 1200°C and that the main phase was 3C-SiC. The XPS results suggested that the SiC nanoparticles were formed by a chemical reaction of Si provided from Si3N4 with free carbon obtained by pyrolysis of polymer. The XPS results also indicated that residual carbon reacted with N2 to form CNx, which remained as an impurity phase in the final product.

AB - We have synthesized Si3N4/SiC nanocomposites using a commercial polymer. The formed Si3N4/SiC nanocomposites have been studied using Raman scattering and X-ray photoelectron spectroscopy (XPS). The Raman scattering measurements showed that the formation of SiC started at 1200°C and that the main phase was 3C-SiC. The XPS results suggested that the SiC nanoparticles were formed by a chemical reaction of Si provided from Si3N4 with free carbon obtained by pyrolysis of polymer. The XPS results also indicated that residual carbon reacted with N2 to form CNx, which remained as an impurity phase in the final product.

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U2 - 10.1016/S0925-8388(99)00007-9

DO - 10.1016/S0925-8388(99)00007-9

M3 - Article

AN - SCOPUS:0033099132

VL - 285

SP - 255

EP - 259

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

IS - 1-2 Complete

ER -

Characterization of Si₃N₄/SiC nanocomposite by Raman scattering and XPS

Abstract

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