Characterizations of polybenzimidazole based electrochemical hydrogen pumps with various Pt loadings for H2/CO2 gas separation

Soo Jin Kim, Byung Seok Lee, Sang Hyun Ahn, Jun Young Han, Hee Young Park, Sung Hyun Kim, Sung Jong Yoo, Hyoung Juhn Kim, Eunae Cho, Dirk Henkensmeier, SukWoo Nam, Tae Hoon Lim, Soo Kil Kim, Wansoo Huh, Jong Hyun Jang

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Carbon capture and storage (CCS) technologies have been intensively researched and developed to cope with climate change, by reducing atmospheric CO2 concentration. The electrochemical hydrogen pumps with phosphoric acid doped polybenzimidazole (PBI) membrane are evaluated as a process to concentrate CO2 and produce pure H2 from anode outlet gases (H2/CO2 mixture) of molten carbonate fuel cells (MCFC). The PBI-based hydrogen pump without humidification (160 C) can provide higher hydrogen separation performances than the cells with perfluorosulfonic- acid membranes at a relative humidity of 43% (80 C), suggesting that the pre-treatment steps can be decreased for PBI-based systems. With the H 2/CO2 mixture feed, the current efficiency for the hydrogen separation is very high, but the cell voltage increase, compared to the pure hydrogen operation, mainly due to the larger polarization resistance at electrodes, as confirmed by electrochemical impedance spectroscopy (EIS). The performance evaluation with various Pt loadings indicates that the hydrogen oxidation reaction at anodes is rate determining, and therefore the Pt loading at cathodes can be decreased from 1.1 mg/cm2 to 0.2 mg/cm2 without significant performance decay. The EIS analysis also confirms that the polarization resistances are largely dependent on the Pt loading in anodes.

Original languageEnglish
Pages (from-to)14816-14823
Number of pages8
JournalInternational Journal of Hydrogen Energy
Volume38
Issue number34
DOIs
Publication statusPublished - 2013 Nov 13

Fingerprint

polybenzimidazole
Pumps
pumps
Hydrogen
hydrogen
Gases
gases
Anodes
anodes
Electrochemical impedance spectroscopy
molten carbonate fuel cells
impedance
Polarization
membranes
Membranes
Molten carbonate fuel cells (MCFC)
Carbon capture
phosphoric acid
Phosphoric acid
climate change

Keywords

  • Carbon capture and storage
  • Electrochemical hydrogen pump
  • Electrochemical impedance spectroscopy
  • Gas separation
  • Polybenzimidazole membranes

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Characterizations of polybenzimidazole based electrochemical hydrogen pumps with various Pt loadings for H2/CO2 gas separation. / Kim, Soo Jin; Lee, Byung Seok; Ahn, Sang Hyun; Han, Jun Young; Park, Hee Young; Kim, Sung Hyun; Yoo, Sung Jong; Kim, Hyoung Juhn; Cho, Eunae; Henkensmeier, Dirk; Nam, SukWoo; Lim, Tae Hoon; Kim, Soo Kil; Huh, Wansoo; Jang, Jong Hyun.

In: International Journal of Hydrogen Energy, Vol. 38, No. 34, 13.11.2013, p. 14816-14823.

Research output: Contribution to journalArticle

Kim, SJ, Lee, BS, Ahn, SH, Han, JY, Park, HY, Kim, SH, Yoo, SJ, Kim, HJ, Cho, E, Henkensmeier, D, Nam, S, Lim, TH, Kim, SK, Huh, W & Jang, JH 2013, 'Characterizations of polybenzimidazole based electrochemical hydrogen pumps with various Pt loadings for H2/CO2 gas separation', International Journal of Hydrogen Energy, vol. 38, no. 34, pp. 14816-14823. https://doi.org/10.1016/j.ijhydene.2013.08.142
Kim, Soo Jin ; Lee, Byung Seok ; Ahn, Sang Hyun ; Han, Jun Young ; Park, Hee Young ; Kim, Sung Hyun ; Yoo, Sung Jong ; Kim, Hyoung Juhn ; Cho, Eunae ; Henkensmeier, Dirk ; Nam, SukWoo ; Lim, Tae Hoon ; Kim, Soo Kil ; Huh, Wansoo ; Jang, Jong Hyun. / Characterizations of polybenzimidazole based electrochemical hydrogen pumps with various Pt loadings for H2/CO2 gas separation. In: International Journal of Hydrogen Energy. 2013 ; Vol. 38, No. 34. pp. 14816-14823.
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abstract = "Carbon capture and storage (CCS) technologies have been intensively researched and developed to cope with climate change, by reducing atmospheric CO2 concentration. The electrochemical hydrogen pumps with phosphoric acid doped polybenzimidazole (PBI) membrane are evaluated as a process to concentrate CO2 and produce pure H2 from anode outlet gases (H2/CO2 mixture) of molten carbonate fuel cells (MCFC). The PBI-based hydrogen pump without humidification (160 C) can provide higher hydrogen separation performances than the cells with perfluorosulfonic- acid membranes at a relative humidity of 43{\%} (80 C), suggesting that the pre-treatment steps can be decreased for PBI-based systems. With the H 2/CO2 mixture feed, the current efficiency for the hydrogen separation is very high, but the cell voltage increase, compared to the pure hydrogen operation, mainly due to the larger polarization resistance at electrodes, as confirmed by electrochemical impedance spectroscopy (EIS). The performance evaluation with various Pt loadings indicates that the hydrogen oxidation reaction at anodes is rate determining, and therefore the Pt loading at cathodes can be decreased from 1.1 mg/cm2 to 0.2 mg/cm2 without significant performance decay. The EIS analysis also confirms that the polarization resistances are largely dependent on the Pt loading in anodes.",
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