Charge transport of camphor sulfonic acid-doped polyaniline and poly(o-toluidine) fibers: role of processing

Y. Z. Wang; J. Joo; C. H. Hsu; A. J. Epstein

doi:10.1016/0379-6779(94)02304-H

Charge transport of camphor sulfonic acid-doped polyaniline and poly(o-toluidine) fibers: role of processing

Y. Z. Wang, J. Joo, C. H. Hsu, A. J. Epstein

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

We report the results of transport studies (temperature-dependent d.c. conductivity, thermopower, microwave frequency conductivity and dielectric constant for camphor sulfonic acid-doped polyaniline (PAN-CSA) and its methyl ring-substituted derivative, poly(o-toluidine) (POT-CSA) fibers prepared in solutions of m-cresol. The results for the PAN-CSA fiber are very similar to those for PAN-CSA film with the presence of some poorer conducting linkages. The POT-CSA fiber shows significantly higher conductivity with much weaker temperature dependence than the earlier studied hydrochloric acid-doped poly(o-toluidine) (POT-HCl) fiber and powder, indicating that it is much closer to the localization-delocalization boundary.

Original language	English
Pages (from-to)	207-211
Number of pages	5
Journal	Synthetic Metals
Volume	68
Issue number	3
DOIs	https://doi.org/10.1016/0379-6779(94)02304-H
Publication status	Published - 1995 Feb
Externally published	Yes

Keywords

Camphor sulfonic acid
Charge transport
Doping
Fibers
Poly(o-toluidine)
Polyaniline

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/0379-6779(94)02304-H

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@article{9038ae732f8a4333abb508e4c74bdcf8,

title = "Charge transport of camphor sulfonic acid-doped polyaniline and poly(o-toluidine) fibers: role of processing",

abstract = "We report the results of transport studies (temperature-dependent d.c. conductivity, thermopower, microwave frequency conductivity and dielectric constant for camphor sulfonic acid-doped polyaniline (PAN-CSA) and its methyl ring-substituted derivative, poly(o-toluidine) (POT-CSA) fibers prepared in solutions of m-cresol. The results for the PAN-CSA fiber are very similar to those for PAN-CSA film with the presence of some poorer conducting linkages. The POT-CSA fiber shows significantly higher conductivity with much weaker temperature dependence than the earlier studied hydrochloric acid-doped poly(o-toluidine) (POT-HCl) fiber and powder, indicating that it is much closer to the localization-delocalization boundary.",

keywords = "Camphor sulfonic acid, Charge transport, Doping, Fibers, Poly(o-toluidine), Polyaniline",

author = "Wang, {Y. Z.} and J. Joo and Hsu, {C. H.} and Epstein, {A. J.}",

note = "Funding Information: This work is supporteidn part by the Officeo f Naval Researcha nd The Ohio State UniversityC enterfor Materials Research.W e appreciated iscussionsw ith J.P. Pouget.C .-H.H. would like to acknowledgJe.S . DiCristofarof or his assistancein preparationo f the fibers.",

year = "1995",

month = feb,

doi = "10.1016/0379-6779(94)02304-H",

language = "English",

volume = "68",

pages = "207--211",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "3",

}

TY - JOUR

T1 - Charge transport of camphor sulfonic acid-doped polyaniline and poly(o-toluidine) fibers

T2 - role of processing

AU - Wang, Y. Z.

AU - Joo, J.

AU - Hsu, C. H.

AU - Epstein, A. J.

N1 - Funding Information: This work is supporteidn part by the Officeo f Naval Researcha nd The Ohio State UniversityC enterfor Materials Research.W e appreciated iscussionsw ith J.P. Pouget.C .-H.H. would like to acknowledgJe.S . DiCristofarof or his assistancein preparationo f the fibers.

PY - 1995/2

Y1 - 1995/2

N2 - We report the results of transport studies (temperature-dependent d.c. conductivity, thermopower, microwave frequency conductivity and dielectric constant for camphor sulfonic acid-doped polyaniline (PAN-CSA) and its methyl ring-substituted derivative, poly(o-toluidine) (POT-CSA) fibers prepared in solutions of m-cresol. The results for the PAN-CSA fiber are very similar to those for PAN-CSA film with the presence of some poorer conducting linkages. The POT-CSA fiber shows significantly higher conductivity with much weaker temperature dependence than the earlier studied hydrochloric acid-doped poly(o-toluidine) (POT-HCl) fiber and powder, indicating that it is much closer to the localization-delocalization boundary.

AB - We report the results of transport studies (temperature-dependent d.c. conductivity, thermopower, microwave frequency conductivity and dielectric constant for camphor sulfonic acid-doped polyaniline (PAN-CSA) and its methyl ring-substituted derivative, poly(o-toluidine) (POT-CSA) fibers prepared in solutions of m-cresol. The results for the PAN-CSA fiber are very similar to those for PAN-CSA film with the presence of some poorer conducting linkages. The POT-CSA fiber shows significantly higher conductivity with much weaker temperature dependence than the earlier studied hydrochloric acid-doped poly(o-toluidine) (POT-HCl) fiber and powder, indicating that it is much closer to the localization-delocalization boundary.

KW - Camphor sulfonic acid

KW - Charge transport

KW - Doping

KW - Fibers

KW - Poly(o-toluidine)

KW - Polyaniline

UR - http://www.scopus.com/inward/record.url?scp=0029244205&partnerID=8YFLogxK

U2 - 10.1016/0379-6779(94)02304-H

DO - 10.1016/0379-6779(94)02304-H

M3 - Article

AN - SCOPUS:0029244205

VL - 68

SP - 207

EP - 211

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 3

ER -

Charge transport of camphor sulfonic acid-doped polyaniline and poly(o-toluidine) fibers: role of processing

Abstract

Keywords

ASJC Scopus subject areas

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