Chemical Effect of Halide Ligands on the Electromechanical Properties of Ag Nanocrystal Thin Films for Wearable Sensors

Junhyuk Ahn, Sanghyun Jeon, Woo Seok Lee, Ho Kun Woo, Donggyu Kim, Junsung Bang, Soong Ju Oh

Research output: Contribution to journalArticle

Abstract

We investigated the chemical effects of halide ligands on the electromechanical properties of Ag nanocrystal (NC) thin films for potential uses in wearable devices and sensors. The halide treatments induced changes in the sizes of sintered NCs, interparticle distances, and microscale surface morphologies. Various characterization techniques and models were used to study the origin of nanoscale and microscale structures, their surface chemistries, and their effects on the electronic and electromechanical properties of the Ag NC thin films. The results indicated that the halide treatments led to changes in the electromechanical gauge factor, which varied from 5 to 600. On the basis of these controllable properties, stable wearable electrodes and sensitive gauge sensors were fabricated. Finally, through all-solution processing, we fabricated directly readable wearable circuits and highly sensitive sensors, in which the motion is detected by the intensity of light through the naked eye. We believe that this work will provide fundamental understanding of the chemical effects of nanostructures on electromechanical properties and a pathway to developing a low-cost, high-performance wearable technology.

Original languageEnglish
Pages (from-to)18087-18094
Number of pages8
JournalJournal of Physical Chemistry C
Volume123
Issue number29
DOIs
Publication statusPublished - 2019 Jul 25

Fingerprint

chemical effects
Nanocrystals
halides
nanocrystals
Ligands
Thin films
ligands
Gages
sensors
Sensors
thin films
microbalances
Surface chemistry
Surface morphology
Nanostructures
Electrodes
Networks (circuits)
chemistry
Processing
electrodes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Chemical Effect of Halide Ligands on the Electromechanical Properties of Ag Nanocrystal Thin Films for Wearable Sensors. / Ahn, Junhyuk; Jeon, Sanghyun; Lee, Woo Seok; Woo, Ho Kun; Kim, Donggyu; Bang, Junsung; Oh, Soong Ju.

In: Journal of Physical Chemistry C, Vol. 123, No. 29, 25.07.2019, p. 18087-18094.

Research output: Contribution to journalArticle

Ahn, Junhyuk ; Jeon, Sanghyun ; Lee, Woo Seok ; Woo, Ho Kun ; Kim, Donggyu ; Bang, Junsung ; Oh, Soong Ju. / Chemical Effect of Halide Ligands on the Electromechanical Properties of Ag Nanocrystal Thin Films for Wearable Sensors. In: Journal of Physical Chemistry C. 2019 ; Vol. 123, No. 29. pp. 18087-18094.
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