Chiral environment of catalytic sites in the chiral metal-organic frameworks

Misun Lee, Sung Min Shin, Nakcheol Jeong, Praveen K. Thallapally

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

Original languageEnglish
Pages (from-to)9349-9352
Number of pages4
JournalDalton Transactions
Volume44
Issue number20
DOIs
Publication statusPublished - 2015 May 28

Fingerprint

Enantioselectivity
Catalysis
Catalytic Domain
Metals
Single crystals

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Chiral environment of catalytic sites in the chiral metal-organic frameworks. / Lee, Misun; Shin, Sung Min; Jeong, Nakcheol; Thallapally, Praveen K.

In: Dalton Transactions, Vol. 44, No. 20, 28.05.2015, p. 9349-9352.

Research output: Contribution to journalArticle

Lee, Misun ; Shin, Sung Min ; Jeong, Nakcheol ; Thallapally, Praveen K. / Chiral environment of catalytic sites in the chiral metal-organic frameworks. In: Dalton Transactions. 2015 ; Vol. 44, No. 20. pp. 9349-9352.
@article{d2744eb0fa7a47feae5be37413497ab0,
title = "Chiral environment of catalytic sites in the chiral metal-organic frameworks",
abstract = "Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.",
author = "Misun Lee and Shin, {Sung Min} and Nakcheol Jeong and Thallapally, {Praveen K.}",
year = "2015",
month = "5",
day = "28",
doi = "10.1039/c5dt01322d",
language = "English",
volume = "44",
pages = "9349--9352",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "20",

}

TY - JOUR

T1 - Chiral environment of catalytic sites in the chiral metal-organic frameworks

AU - Lee, Misun

AU - Shin, Sung Min

AU - Jeong, Nakcheol

AU - Thallapally, Praveen K.

PY - 2015/5/28

Y1 - 2015/5/28

N2 - Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

AB - Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

UR - http://www.scopus.com/inward/record.url?scp=84930673123&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84930673123&partnerID=8YFLogxK

U2 - 10.1039/c5dt01322d

DO - 10.1039/c5dt01322d

M3 - Article

AN - SCOPUS:84930673123

VL - 44

SP - 9349

EP - 9352

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 20

ER -