Chiral hybrid metal-organic dendrimers

Hua Jiang, Suk Joong Lee, Wenbin Lin

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

(matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.

Original languageEnglish
Pages (from-to)2149-2152
Number of pages4
JournalOrganic Letters
Volume4
Issue number13
DOIs
Publication statusPublished - 2002 Jun 27
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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