Chiral hybrid metal-organic dendrimers

Hua Jiang; Suk Joong Lee; Wenbin Lin

doi:10.1021/ol0259037

Chiral hybrid metal-organic dendrimers

Hua Jiang, Suk Joong Lee, Wenbin Lin

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

(matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)₂]²⁺ unit.

Original language	English
Pages (from-to)	2149-2152
Number of pages	4
Journal	Organic Letters
Volume	4
Issue number	13
DOIs	https://doi.org/10.1021/ol0259037
Publication status	Published - 2002 Jun 27
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0259037

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title = "Chiral hybrid metal-organic dendrimers",

abstract = "(matrix presented) New chiral terpyridines containing Frech{\'e}t-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.",

author = "Hua Jiang and Lee, {Suk Joong} and Wenbin Lin",

year = "2002",

month = jun,

day = "27",

doi = "10.1021/ol0259037",

language = "English",

volume = "4",

pages = "2149--2152",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Chiral hybrid metal-organic dendrimers

AU - Jiang, Hua

AU - Lee, Suk Joong

AU - Lin, Wenbin

PY - 2002/6/27

Y1 - 2002/6/27

N2 - (matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.

AB - (matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.

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EP - 2152

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 13

ER -

Chiral hybrid metal-organic dendrimers

Abstract

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