Abstract
(matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.
| Original language | English |
|---|---|
| Pages (from-to) | 2149-2152 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 4 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - 2002 Jun 27 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
Cite this
Chiral hybrid metal-organic dendrimers. / Jiang, Hua; Lee, Suk Joong; Lin, Wenbin.
In: Organic Letters, Vol. 4, No. 13, 27.06.2002, p. 2149-2152.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chiral hybrid metal-organic dendrimers
AU - Jiang, Hua
AU - Lee, Suk Joong
AU - Lin, Wenbin
PY - 2002/6/27
Y1 - 2002/6/27
N2 - (matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.
AB - (matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.
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UR - http://www.scopus.com/inward/citedby.url?scp=0038813262&partnerID=8YFLogxK
U2 - 10.1021/ol0259037
DO - 10.1021/ol0259037
M3 - Article
VL - 4
SP - 2149
EP - 2152
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 13
ER -