Abstract
(matrix presented) New chiral terpyridines containing Frechét-type dendrons have been readily synthesized by coupling dendritic benzyl bromide and 4′-[6-(2,2′-dihydroxy-1,1′-binaphthyl)]-2,2′: 6′2″-terpyridine. These chiral dendritic terpyridines were used to efficiently construct high molecular weight hybrid metal-organic dendrimers based on the Ru(II)-bis(terpy) linkage. Preliminary fluorescence measurements show generation-dependent fluorescence quenching behavior of 3,5-dimethoxybenzyl peripherals by the [Ru(terpy)2]2+ unit.
| Original language | English |
|---|---|
| Pages (from-to) | 2149-2152 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 4 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - 2002 Jun 27 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
Fingerprint Dive into the research topics of 'Chiral hybrid metal-organic dendrimers'. Together they form a unique fingerprint.
Cite this
Jiang, H., Lee, S. J., & Lin, W. (2002). Chiral hybrid metal-organic dendrimers. Organic Letters, 4(13), 2149-2152. https://doi.org/10.1021/ol0259037