Co-electrospinning of core-shell fibers using a single-nozzle technique

Alexander V. Bazilevsky, Alexander L. Yarin, Constantine M. Megaridis

Research output: Contribution to journalArticle

244 Citations (Scopus)

Abstract

Co-electrospinning is ideally suited for fabricating continuous fibers encasing materials within a polymer sleeve, but requires relatively complex coannular nozzles. A single-nozzle co-electrospinning technique is demonstrated using blends of poly(methyl methacrylate) (PMMA)/polyacrylonitrile (PAN) solutions in dimethylformamide (DMF). The as-spun fibers have outer diameters in the range of 0.5-5 μm and possess a core-shell structure similar to that attained via coannular nozzles. The technique relies on the precipitation of PMMA solution droplets, which become trapped at the base of the Taylor cone issuing the PAN solution jet from its tip. A theoretical analysis shows that the outer shell flow is sufficiently strong to stretch the inner droplet into the Taylor cone, thus forming a core-shell jet. The method seems attractive for technological applications involving macroscopically long and radially inhomogeneous or hollow nano/micro fibers.

Original languageEnglish
Pages (from-to)2311-2314
Number of pages4
JournalLangmuir
Volume23
Issue number5
DOIs
Publication statusPublished - 2007 Feb 27

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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    Bazilevsky, A. V., Yarin, A. L., & Megaridis, C. M. (2007). Co-electrospinning of core-shell fibers using a single-nozzle technique. Langmuir, 23(5), 2311-2314. https://doi.org/10.1021/la063194q