Cobalt and cerium coated Ni powder as a new candidate cathode material for MCFC

Min Hyuk Kim, Ming Zi Hong, Young Suk Kim, Eunjoo Park, Hyunsuk Lee, Hyung Wook Ha, Keon Kim

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23 Citations (Scopus)

Abstract

The dissolution of nickel oxide cathode in the electrolyte is one of the major technical obstacles to the commercialization of molten carbonate fuel cell (MCFC). To improve the MCFC cathode stability, the alternative cathode material for MCFC was prepared, which was made of Co/Ce-coated on the surface of Ni powder using a polymeric precursor based on the Pechini method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDAX) were employed in characterization of the alternative cathode materials. The Co/Ce-coated Ni cathode prepared by the tape-casting technique. The solubility of the Co/Ce-coated Ni cathode was about 80% lower when compare to that of pure Ni cathode under CO2:O2 (66.7:33.3%) atmosphere at 650 °C. Consequently, the fine Co/Ce-coated Ni powder could be confirmed as a new alternative cathode material for MCFC.

Original languageEnglish
Pages (from-to)6145-6151
Number of pages7
JournalElectrochimica Acta
Volume51
Issue number27
DOIs
Publication statusPublished - 2006 Aug 25

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Keywords

  • Cathode
  • Co/Ce-coated Ni powder
  • MCFC
  • Pechini method
  • Solubility

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

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