Coexistence of spin canting and metamagnetism in a one-dimensional Mn(III) complex bridged by a single end-to-end azide

Hee Ko Hyun, Hak Lim Jeong, Chan Kim Hyoung, Seop Hong Chang

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.

Original languageEnglish
Pages (from-to)8847-8849
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number22
DOIs
Publication statusPublished - 2006 Oct 30

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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