Coexistence of spin canting and metamagnetism in a one-dimensional Mn(III) complex bridged by a single end-to-end azide

Hee Ko Hyun, Hak Lim Jeong, Chan Kim Hyoung, Chang Seop Hong

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17 Citations (Scopus)

Abstract

Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.

Original languageEnglish
Pages (from-to)8847-8849
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number22
DOIs
Publication statusPublished - 2006 Oct 30

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ASJC Scopus subject areas

  • Inorganic Chemistry

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