Compositional data analysis and geochemical modeling of CO2–water–rock interactions in three provinces of Korea

Seong Hee Kim, Byoung Young Choi, Gyemin Lee, Seong Taek Yun, Soon Oh Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The CO2-rich spring water (CSW) occurring naturally in three provinces, Kangwon (KW), Chungbuk (CB), and Gyeongbuk (GB) of South Korea was classified based on its hydrochemical properties using compositional data analysis. Additionally, the geochemical evolution pathways of various CSW were simulated via equilibrium phase modeling (EPM) incorporated in the PHREEQC code. Most of the CSW in the study areas grouped into the Ca–HCO3 water type, but some samples from the KW area were classified as Na–HCO3 water. Interaction with anorthite is likely to be more important than interaction with carbonate minerals for the hydrochemical properties of the CSW in the three areas, indicating that the CSW originated from interactions among magmatic CO2, deep groundwater, and bedrock-forming minerals. Based on the simulation results of PHREEQC EPM, the formation temperatures of the CSW within each area were estimated as 77.8 and 150 °C for the Ca–HCO3 and Na–HCO3 types of CSW, respectively, in the KW area; 138.9 °C for the CB CSW; and 93.0 °C for the GB CSW. Additionally, the mixing ratios between simulated carbonate water and shallow groundwater were adjusted to 1:9–9:1 for the CSW of the GB area and the Ca–HCO3-type CSW of the KW area, indicating that these CSWs were more affected by carbonate water than by shallow groundwater. On the other hand, mixing ratios of 1:9–5:5 and 1:9–3:7 were found for the Na–HCO3-type CSW of the KW area and for the CSW of the CB area, respectively, suggesting a relatively small contribution of carbonate water to these CSWs. This study proposes a systematic, but relatively simple, methodology to simulate the formation of carbonate water in deep environments and the geochemical evolution of CSW. Moreover, the proposed methodology could be applied to predict the behavior of CO2 after its geological storage and to estimate the stability and security of geologically stored CO2.

Original languageEnglish
Pages (from-to)1-24
Number of pages24
JournalEnvironmental Geochemistry and Health
DOIs
Publication statusAccepted/In press - 2017 Dec 20

Fingerprint

Springs (water)
spring water
modeling
Carbonates
Water
carbonate
Groundwater
phase equilibrium
data analysis
province
mixing ratio
Phase equilibria
water
groundwater
Carbonate minerals
methodology
anorthite
mineral
Minerals

Keywords

  • CO-rich spring water
  • CO–water–rock interaction
  • Compositional data analysis
  • Equilibrium phase modeling
  • Geological CO storage

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Water Science and Technology
  • Environmental Science(all)
  • Geochemistry and Petrology

Cite this

Compositional data analysis and geochemical modeling of CO2–water–rock interactions in three provinces of Korea. / Kim, Seong Hee; Choi, Byoung Young; Lee, Gyemin; Yun, Seong Taek; Kim, Soon Oh.

In: Environmental Geochemistry and Health, 20.12.2017, p. 1-24.

Research output: Contribution to journalArticle

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abstract = "The CO2-rich spring water (CSW) occurring naturally in three provinces, Kangwon (KW), Chungbuk (CB), and Gyeongbuk (GB) of South Korea was classified based on its hydrochemical properties using compositional data analysis. Additionally, the geochemical evolution pathways of various CSW were simulated via equilibrium phase modeling (EPM) incorporated in the PHREEQC code. Most of the CSW in the study areas grouped into the Ca–HCO3 water type, but some samples from the KW area were classified as Na–HCO3 water. Interaction with anorthite is likely to be more important than interaction with carbonate minerals for the hydrochemical properties of the CSW in the three areas, indicating that the CSW originated from interactions among magmatic CO2, deep groundwater, and bedrock-forming minerals. Based on the simulation results of PHREEQC EPM, the formation temperatures of the CSW within each area were estimated as 77.8 and 150 °C for the Ca–HCO3 and Na–HCO3 types of CSW, respectively, in the KW area; 138.9 °C for the CB CSW; and 93.0 °C for the GB CSW. Additionally, the mixing ratios between simulated carbonate water and shallow groundwater were adjusted to 1:9–9:1 for the CSW of the GB area and the Ca–HCO3-type CSW of the KW area, indicating that these CSWs were more affected by carbonate water than by shallow groundwater. On the other hand, mixing ratios of 1:9–5:5 and 1:9–3:7 were found for the Na–HCO3-type CSW of the KW area and for the CSW of the CB area, respectively, suggesting a relatively small contribution of carbonate water to these CSWs. This study proposes a systematic, but relatively simple, methodology to simulate the formation of carbonate water in deep environments and the geochemical evolution of CSW. Moreover, the proposed methodology could be applied to predict the behavior of CO2 after its geological storage and to estimate the stability and security of geologically stored CO2.",
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AU - Kim, Soon Oh

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N2 - The CO2-rich spring water (CSW) occurring naturally in three provinces, Kangwon (KW), Chungbuk (CB), and Gyeongbuk (GB) of South Korea was classified based on its hydrochemical properties using compositional data analysis. Additionally, the geochemical evolution pathways of various CSW were simulated via equilibrium phase modeling (EPM) incorporated in the PHREEQC code. Most of the CSW in the study areas grouped into the Ca–HCO3 water type, but some samples from the KW area were classified as Na–HCO3 water. Interaction with anorthite is likely to be more important than interaction with carbonate minerals for the hydrochemical properties of the CSW in the three areas, indicating that the CSW originated from interactions among magmatic CO2, deep groundwater, and bedrock-forming minerals. Based on the simulation results of PHREEQC EPM, the formation temperatures of the CSW within each area were estimated as 77.8 and 150 °C for the Ca–HCO3 and Na–HCO3 types of CSW, respectively, in the KW area; 138.9 °C for the CB CSW; and 93.0 °C for the GB CSW. Additionally, the mixing ratios between simulated carbonate water and shallow groundwater were adjusted to 1:9–9:1 for the CSW of the GB area and the Ca–HCO3-type CSW of the KW area, indicating that these CSWs were more affected by carbonate water than by shallow groundwater. On the other hand, mixing ratios of 1:9–5:5 and 1:9–3:7 were found for the Na–HCO3-type CSW of the KW area and for the CSW of the CB area, respectively, suggesting a relatively small contribution of carbonate water to these CSWs. This study proposes a systematic, but relatively simple, methodology to simulate the formation of carbonate water in deep environments and the geochemical evolution of CSW. Moreover, the proposed methodology could be applied to predict the behavior of CO2 after its geological storage and to estimate the stability and security of geologically stored CO2.

AB - The CO2-rich spring water (CSW) occurring naturally in three provinces, Kangwon (KW), Chungbuk (CB), and Gyeongbuk (GB) of South Korea was classified based on its hydrochemical properties using compositional data analysis. Additionally, the geochemical evolution pathways of various CSW were simulated via equilibrium phase modeling (EPM) incorporated in the PHREEQC code. Most of the CSW in the study areas grouped into the Ca–HCO3 water type, but some samples from the KW area were classified as Na–HCO3 water. Interaction with anorthite is likely to be more important than interaction with carbonate minerals for the hydrochemical properties of the CSW in the three areas, indicating that the CSW originated from interactions among magmatic CO2, deep groundwater, and bedrock-forming minerals. Based on the simulation results of PHREEQC EPM, the formation temperatures of the CSW within each area were estimated as 77.8 and 150 °C for the Ca–HCO3 and Na–HCO3 types of CSW, respectively, in the KW area; 138.9 °C for the CB CSW; and 93.0 °C for the GB CSW. Additionally, the mixing ratios between simulated carbonate water and shallow groundwater were adjusted to 1:9–9:1 for the CSW of the GB area and the Ca–HCO3-type CSW of the KW area, indicating that these CSWs were more affected by carbonate water than by shallow groundwater. On the other hand, mixing ratios of 1:9–5:5 and 1:9–3:7 were found for the Na–HCO3-type CSW of the KW area and for the CSW of the CB area, respectively, suggesting a relatively small contribution of carbonate water to these CSWs. This study proposes a systematic, but relatively simple, methodology to simulate the formation of carbonate water in deep environments and the geochemical evolution of CSW. Moreover, the proposed methodology could be applied to predict the behavior of CO2 after its geological storage and to estimate the stability and security of geologically stored CO2.

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