Conformational study of a rigid-structured octathiabiscavitand from [2 + 2] coupling of caps and bridging units

Lee Jungbai, Kihang Choi, Kyungsoo Pack

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

An octathiacavitand was stereoselectively obtained in good yield by [2 + 2] coupling reaction between a tetrakis(thiomethyl)cavitand and 1,2,4,5- tetrakis(bromomethyl)benzene. Its NOESY spectrum showed that its cavity was divided into two small ones by π - π stacking of two bridging benzene units.

Original languageEnglish
Pages (from-to)8203-8206
Number of pages4
JournalTetrahedron Letters
Volume38
Issue number47
DOIs
Publication statusPublished - 1997 Nov 24
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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